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US 12,653,186 B2Granted
[(1-phenyl-5-(heteroaryl)-1H-1,2,4-triazol-3-yl)oxy] acetic acid derivatives as safeners for the protection of useful plants and crop plants
AssigneeBayer Aktiengesellschaft
InventorsThomas Müller, Anna Maria Reingruber, Jens Frackenpohl, Hendrik Helmke, Jan Dittgen
Life of this patent
Estimating the term…
Abstract
The present invention relates to crop protection compounds and to compositions which comprise specific compounds as safeners for reducing phytotoxic effects of agrochemicals, especially herbicides. The invention relates more particularly to certain [(1-phenyl-5-(heteroaryl)-1H-1,2,4-triazol-3-yl)oxy]acetic acid derivatives of the general formula (I) and their salts, to processes for preparing them and to their use as crop protection compounds (safeners).
Claims16
A compound of general formula (I) or salt thereof
- in which
- R1 is heteroaryl, where the heteroaryl radical is unsubstituted or substituted by halogen, cyano, nitro, (C1-C6)alkyl, (C2-C6)alkenyl, (C2-C6)alkynyl, (C3-C8)cycloalkyl, (C3-C8)cycloalkenyl, (C1-C6)alkoxy or (C1-C6)alkylS(O)p, where the latter seven radicals are unsubstituted or are substituted by one or more radicals from the group of halogen, cyano, (C1-C6)alkoxy and (C1-C6)alkylS(O)p,
- R2 is hydrogen, halogen, cyano, nitro, (C1-C6)alkyl, (C2-C6)alkenyl, (C2-C6)alkynyl, (C3-C8)cycloalkyl, (C3-C8)cycloalkenyl, (C1-C6)alkoxy or (C1-C6)alkylS(O)p, where the latter seven radicals are unsubstituted or are substituted by one or more radicals from the group of halogen, cyano, (C1-C6)alkoxy and (C1-C6)alkylS(O)p,
- R3 is hydrogen or (C1-C6)alkyl,
- R4 is hydrogen, (C1-C18)alkyl, (C1-C18)haloalkyl, (C1-C18)cyanoalkyl, (C2-C18)alkenyl, (C2-C18)alkynyl, (C3-C12)cycloalkyl, (C3-C12)cycloalkenyl, aryl, heteroaryl, (C1-C18)alkoxy-(C1-C18)alkyl, (C1-C18)haloalkoxy-(C1-C18)alkyl, (C1-C18)alkoxy-(C1-C18)haloalkyl, (C1-C18)alkylthio-(C1-C18)alkyl, (C1-C18)haloalkylthio-(C1-C18)alkyl, (C2-C18)haloalkenyl, (C2-C18)haloalkynyl, heterocyclyl-(C1-C18)alkyl, aryl-(C1-C18)alkyl, (C3-C12)cycloalkyl-(C1-C18)alkyl, (C1-C18)alkoxycarbonyl-(C1-C18)alkyl, or (C1-C18)alkoxycarbonyl-(C3-C12)cycloalkyl-(C1-C18)alkyl, or
- a radical of the formula —NRaRb or —N═CRcRd,
- where, in the former 2 radicals, each of the Ra, Rb, Rc and Rd radicals is independently hydrogen, (C1-C4)alkyl, (C2-C4)alkenyl, (C2-C4)alkynyl, benzyl, substituted benzyl, phenyl or substituted phenyl,
- or Ra and Rb together with the nitrogen atom may form a 3- to 8-membered heterocycle which, in addition to the nitrogen atom, may contain one or two further ring heteroatoms from the group of N, O and S and which is unsubstituted or substituted by one or more radicals from the group of (C1-C4)-alkyl and (C1-C4)-haloalkyl,
- or Rc and Rd together with the carbon atom are a 3- to 8-membered carbocyclic or heterocyclic radical which may contain 1 to 3 ring heteroatoms from the group of N, O and S, where the carbocyclic or heterocyclic radical is unsubstituted or substituted by one or more radicals from the group of (C1-C4)-alkyl and (C1-C4)-haloalkyl,
- m is a number from 0 to 5,
- and
- p is 0, 1 or 2.
9 more elements
Dependencies are inferred from the claim text.