Carbon neutral hydrogen production
AssigneeSaudi Arabian Oil Company
InventorJohn O'Connell
Life of this patent
Estimating the term…
Abstract
A hydrocarbon stream is combusted within a reactor to produce soot and syngas. Sub-stoichiometric combustion of the hydrocarbon stream within the reactor converts at least 10% of the carbon in the hydrocarbon stream into soot. The syngas is mixed with a steam stream to produce a hydrogenation feed stream. A shift reactor converts at least a portion of the carbon monoxide and steam to carbon dioxide and hydrogen to produce a shifted gas stream. Water is separated from the shifted gas stream to produce a dehydrated gas stream. The dehydrated gas stream is separated to produce a hydrogen product stream and a recycle stream. The recycle stream is recycled to the reactor.
Claims14
A method comprising:
- flowing a hydrocarbon stream to a reactor, the hydrocarbon stream comprising at least one hydrocarbon;
- flowing an oxidizing stream to the reactor, the oxidizing stream comprising oxygen gas and having a molar flow rate of oxygen gas in a range of from 10% to 70% of C+H/4, wherein C is a molar flow rate of carbon (C) of the hydrocarbon stream, and H is a molar flow rate of hydrogen (H) of the hydrocarbon stream;
- combusting the hydrocarbon stream within the reactor to produce soot and syngas, wherein sub-stoichiometric combustion of the hydrocarbon stream within the reactor converts at least 20% of the carbon in the hydrocarbon stream into soot;
- separating the soot from the syngas to produce a syngas stream comprising carbon dioxide, carbon monoxide, and hydrogen;
- mixing the syngas stream with a steam stream to produce a hydrogenation feed stream;
- contacting the hydrogenation feed stream with a water-gas shift catalyst in a shift reactor to convert at least a portion of the carbon monoxide and steam to carbon dioxide and hydrogen to produce a shifted gas stream;
- separating water from the shifted gas stream to produce a dehydrated gas stream;
- separating the dehydrated gas stream to produce a hydrogen product stream and a recycle stream, the hydrogen product stream comprising a majority of the hydrogen from the dehydrated gas stream, and the recycle stream comprising a remainder of the dehydrated gas stream;
- and
- recycling the recycle stream to the reactor.
Dependencies are inferred from the claim text.