Films, laminates, and methods of making compositions

A method of forming a laminate from a film comprising a first major surface and a second major surface opposite the first major surface, a film thickness defined between the first major surface and the second major surface in a range from about 5 micrometers to about 400 micrometers, the method comprising:

• disposing the second major surface of the film over a third major surface of a substrate, the substrate comprising a fourth major surface opposite the third major surface and a substrate thickness defined between the third major surface and the fourth major surface wherein the substrate comprises a glass-based substrate and/or a ceramic-based substrate;
• applying a first release layer over the first major surface of the film and a second release layer over the fourth major surface of the substrate;
• placing the film and the substrate in a vacuum container;
• heating the film and the substrate at a first temperature in a range from about 40° C. to about 100° C. for a time in a range from about 10 minutes to about 8 hours;
• and
• heating the film and substrate at a second temperature in a range from about 150° C. to about 250° C. at a gauge pressure in a range from about 1.0 MegaPascals to about 1.5 MegaPascals for a time in a range from about 30 minutes to about 2 hours to form the laminate,
• wherein the film comprising a tri-block copolymer comprising a first block positioned between two second blocks, the first block is grafted with a first functional group, the film comprises, based on 100 wt % of the film, from greater than or equal to 45 wt % to less than or equal to 87 wt % of the first block in the tri-block copolymer and from greater than or equal to 8 wt % to 45 wt % of the two second blocks in the tri-block copolymer.