Method to modify the surface of quantum dots and a method to prepare a dispersion of surface modified quantum dots
AssigneeUniversiteit Gent
InventorsZeger Hens, Jari Leemans
Life of this patent
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Abstract
A method to modify the surface of III-V quantum dots. III-V quantum dots provided with X type ligands and L type ligands at their outer surface are dispersed in a solvent include an additional compound. The additional compound has an organic acid of formula RYH or an organic salt of formula RYH+Z− and has at least one acidic proton H+ having a pKa in water equal to or lower than 16. During dispersion the acidic proton H+ protonates at least part of the L type ligands and at least part of the X type ligands are replaced. Surface modified quantum dots, dispersions having such surface modified quantum dots and to the use of such dispersions are disclosed.
Claims7
A method to modify the surface of quantum dots, said method comprising the steps of:
- providing III-V quantum dots, said quantum dots having X type ligands and L type ligands at their outer surface, with X type ligands comprising ligands able to donate one electron to a quantum dot to which the X type ligand is bound and with L type ligands comprising ligands able to donate two electrons to a quantum dot to which the L type ligand is bound;
- dispersing said quantum dots in a solvent further comprising an additional compound to form modified quantum dots, said additional compound comprising an organic acid of formula RYH or an organic salt of formula RYH+Z−, said additional compound comprising at least one acidic proton H+ having a pKa in water equal or lower than 16 and said additional compound comprising a R-group comprising at least one carbon atom, with said organic acid of formula RYH being selected from the group consisting of carboxylic acids, sulfonic acids, thiols and phenols, with said organic salt of formula RYH+Z− comprising an organic ammonium ion RYH+ and a negatively charged counterion Z−;
- whereby during said dispersing said acidic proton H+ of said additional compound protonates at least part of said L type ligands to form protonated L type ligands and at least part of said X type ligands are replaced by deprotonated acid RY− of said organic acid of formula RYH or by counterion Z− of said organic salt of formula RYH+Z− and/or by deprotonated conjugated base RY of ion RYH+ of said organic salt of formula RYH+Z−.
Dependencies are inferred from the claim text.