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US 12,637,523 B2Granted
Polymerization catalyst composition, method for producing polymerization catalyst composition, and method for producing conjugated diene polymer
AssigneesDIC Corporation, National University Corporation Nagaoka University of Technology
InventorsAkinori Takahashi, Hiroaki Nakano, Katsuhiko Takenaka, Tomoyuki Toda
Life of this patent
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Abstract
A polymerization catalyst composition contains a rare earth element carboxylate, a phosphate ester represented by the following general formula (1): [Formula 1] O═P(OR)3 (1) (wherein Rs are each independently an alkyl group having 5 to 20 carbon atoms), and water.
Claims5
A polymerization catalyst composition comprising:
- a rare earth element carboxylate;
- and
- a phosphate ester represented by the following general formula (1), and
- no organoaluminum compound;
- wherein the polymerization catalyst composition is obtained by a method comprising the following steps (a), (b) and (c):
- a step (a) of adjusting a content of a phosphoric acid ester represented by the general formula (1) within a range of 0.01 to 20 eq relative to the rare earth element contained in the rare earth element carboxylate;
- a step (b) of adjusting a content of water to 0.5 eq or less relative to the rare earth element contained in the rare earth element carboxylate at a reaction temperature of 80 to 160° C.;
- and
- a step (c) of adjusting a total content of free fatty acid and water to 0.6 eq or less relative to the rare earth element contained in the rare earth element carboxylate:
- [Formula 1]
- O═P(OR)3 (1)
- wherein Rs are each independently an alkyl group having 5 to 20 carbon atoms;
- and
- wherein a content of the phosphoric acid ester is 0.01 to 20 eq relative to the rare earth element contained in the rare earth element carboxylate.
11 more elements
Dependencies are inferred from the claim text.