Process for preparing battery grade metal sulphate solutions
AssigneesNorthvolt AB, Metal Trade Overseas AG
InventorsCornelia Lantto, Tom Niemi, Pekka Alisaari, Esa Lindell, Rauno Luoma, Tuomo Laukkanen, Pekka Tynjälä, Ulla Lassi
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Abstract
Battery grade metal sulfate solutions can be prepared directly from electrolytically produced metal objects, such as cathode plates, when these are subjected to an aqueous leaching solution comprising at least one acid leaching agent and a liquid oxidizing agent in a continuous process at elevated temperature and with vigorous mixing. A leaching arrangement comprising a leaching column or reaction vessel is also disclosed.
Claims18
A process for preparing battery grade metal sulfate solutions, wherein electrolytically produced metal objects are introduced in a first direction and subjected to an aqueous leaching solution at an elevated temperature and acid pH in a continuous process with mixing, said leaching solution comprising at least one acid leaching agent and an oxidizing agent in liquid form, wherein said mixing is achieved by recirculating the aqueous leaching solution that is introduced in a second direction through a leaching column operating in counter-current mode, said second direction being opposite said first direction, said electrolytically produced metal objects being introduced in said first direction at a top of said leaching column while said leaching solution is being introduced in said second direction at a bottom of said leaching column, said bottom being opposite said top, and said opposing direction of introduction at said top and said bottom, respectively, and said counter-current mode resulting therefrom causing shearing and enhancing leaching.
A process for preparing battery grade metal sulfate solutions, wherein electrolytically produced metal objects are subjected to an aqueous leaching solution at an elevated temperature and acid pH in a continuous process with mixing, said leaching solution comprising at least one acid leaching agent and an oxidizing agent pre-mixed in liquid form, wherein said mixing is achieved by recirculating the aqueous leaching solution through a leaching column operating in counter-current mode, wherein said counter-current mode causes shearing and enhances leaching, wherein said electrolytically produced metal objects are introduced at a top of the leaching column while said leaching solution is introduced at a bottom of the leaching column opposite the top, and wherein the pH is maintained in a range of 1-6 during leaching with the oxidizing agent.
Dependencies are inferred from the claim text.