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US 12,631,616 B2Granted
Method of analyzing copolycarbonate
AssigneeLG Chem, Ltd.
InventorsHyo Yong Kim, Jin Sook Ryu, Sunok Oh, Sung Joon Oh
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Abstract
Provided is a method of analyzing a copolycarbonate. More particularly, provided is a method of analyzing a copolycarbonate, in which a polysiloxane structure is introduced into the main chain of a polycarbonate, the method capable of more accurately analyzing a weight average molecular weight, a number average molecular weight, and a molecular weight distribution of a polysiloxane-containing aromatic diol compound which is used as a starting material.
Claims8
A method of analyzing a copolycarbonate, the method comprising:
- reacting the copolycarbonate including a first repeating unit derived from an aromatic diol compound and a second repeating unit derived from a polysiloxane-containing aromatic diol compound with methanol to decompose the copolycarbonate into the aromatic diol compound and the polysiloxane-containing aromatic diol compound;
- and
- performing gel permeation chromatography (GPC) of the decomposed polysiloxane-containing aromatic diol compound after the reacting step without a separate extraction and/or purification process,
- wherein the step of reacting the copolycarbonate with methanol includes the steps of dissolving an alkali salt in methanol to prepare an alkali hydroxide solution;
- and reacting the prepared alkali hydroxide solution with the copolycarbonate to perform an alkali-catalyzed alcoholysis reaction,
- wherein the alkali-catalyzed alcoholysis reaction is performed at 40° C. to 70° C., and
- wherein the step of performing GPC of the decomposed polysiloxane-containing aromatic diol compound is performed by quenching a decomposition product including the decomposed polysiloxane-containing aromatic diol compound using liquid nitrogen and then diluting the product, followed by GPC.
4 more elements
Dependencies are inferred from the claim text.