Cyclic olefin polymer, cyclic olefin polymer monomer, and optical product

A cyclic olefin polymer monomer, wherein a chemical structural formula of the cyclic olefin polymer monomer is shown in Formula (4):

• wherein
• in Formula (4), p and q are integers greater than or equal to 0 and less than or equal to 6;
• x and y are integers greater than or equal to 0;
• p1 and q1 are integers greater than or equal to 0 and less than or equal to 6, and p1 and q1 are not 0 at the same time;
• R1 to R12, Ra, Rb, Rc, and Rd are separately and independently selected from a hydrogen atom, a halogen atom, an alkyl group, an aryl group, an alkoxy group, a hydroxy group, an ester group, a cyano group, an amino group, a thiol group, and an atom or an atomic group that can replace the foregoing group;
• and R13, R14, R15, and R16 are separately and independently selected from the hydrogen atom, the halogen atom, the alkyl group, the aryl group, the alkoxy group, the hydroxy group, the ester group, the cyano group, the amino group, the thiol group, and the atom or the atomic group that can replace the foregoing group;
• or any two, three, or four of R13, R14, R15, and R16 are connected to form a cyclic structure, and a group that does not participate in forming the cyclic structure in R13, R14, R15, and R16 is separately and independently selected from the hydrogen atom, the halogen atom, the alkyl group, the aryl group, the alkoxy group, the hydroxy group, the ester group, the cyano group, the amino group, the thiol group, and the atom or the atomic group that can replace the foregoing group.

An optical material, comprising the cyclic olefin polymer comprising:

• a repeat unit whose structural formula is shown in Formula (1) and a repeat unit whose structural formula is shown in Formula (2):
• wherein
• in Formula (1), p and q are integers greater than or equal to 0 and less than or equal to 6;
• x and y are integers greater than or equal to 0;
• p1 and q1 are integers greater than or equal to 0 and less than or equal to 6, and p1 and q1 are not 0 at the same time;
• R1 to R12, Ra, Rb, Rc, and Rd are separately and independently selected from a hydrogen atom, a halogen atom, an alkyl group, an aryl group, an alkoxy group, a hydroxy group, an ester group, a cyano group, an amino group, a thiol group, and an atom or an atomic group that can replace the foregoing group;
• and R13, R14, R15, and R16 are separately and independently selected from the hydrogen atom, the halogen atom, the alkyl group, the aryl group, the alkoxy group, the hydroxy group, the ester group, the cyano group, the amino group, the thiol group, and the atom or the atomic group that can replace the foregoing group;
• or any two, three, or four of R13, R14, R15, and R16 are connected to form a cyclic structure, and a group that does not participate in forming the cyclic structure in R13, R14, R15, and R16 is separately and independently selected from the hydrogen atom, the halogen atom, the alkyl group, the aryl group, the alkoxy group, the hydroxy group, the ester group, the cyano group, the amino group, the thiol group, and the atom or the atomic group that can replace the foregoing group;
• and
• in Formula (2), p′ and q′ are integers greater than or equal to 0 and less than or equal to 6;
• x′ and y′ are integers greater than or equal to 0;
• p1′ and q1′ are integers greater than or equal to 0 and less than or equal to 6, and p1′ and q1′ are not 0 at the same time;
• R1′ to R12′, Ra′, Rb′, Rc′, and Rd′ are separately and independently selected from the hydrogen atom, the halogen atom, the alkyl group, the aryl group, the alkoxy group, the hydroxy group, the ester group, the cyano group, the amino group, the thiol group, and the atom or the atomic group that can replace the foregoing group;
• and R13′, R14′, R15′, and R16′ are separately and independently selected from the hydrogen atom, the halogen atom, the alkyl group, the aryl group, the alkoxy group, the hydroxy group, the ester group, the cyano group, the amino group, the thiol group, and the atom or the atomic group that can replace the foregoing group;
• or any two, three, or four of R13′, R14′, R15′, and R16′ are connected to form the cyclic structure, and a group that does not participate in forming the cyclic structure in R13′, R14′, R15′, and R16′ is separately and independently selected from the hydrogen atom, the halogen atom, the alkyl group, the aryl group, the alkoxy group, the hydroxy group, the ester group, the cyano group, the amino group, the thiol group, and the atom or the atomic group that can replace the foregoing group.

An optical product, comprising a cyclic olefin polymer comprising:

• a repeat unit whose structural formula is shown in Formula (1) and a repeat unit whose structural formula is shown in Formula (2):
• wherein
• in Formula (1), p and q are integers greater than or equal to 0 and less than or equal to 6;
• x and y are integers greater than or equal to 0;
• p1 and q1 are integers greater than or equal to 0 and less than or equal to 6, and p1 and q1 are not 0 at the same time;
• R1 to R12, Ra, Rb, Rc, and Rd are separately and independently selected from a hydrogen atom, a halogen atom, an alkyl group, an aryl group, an alkoxy group, a hydroxy group, an ester group, a cyano group, an amino group, a thiol group, and an atom or an atomic group that can replace the foregoing group;
• and R13, R14, R15, and R16 are separately and independently selected from the hydrogen atom, the halogen atom, the alkyl group, the aryl group, the alkoxy group, the hydroxy group, the ester group, the cyano group, the amino group, the thiol group, and the atom or the atomic group that can replace the foregoing group;
• or any two, three, or four of R13, R14, R15, and R16 are connected to form a cyclic structure, and a group that does not participate in forming the cyclic structure in R13, R14, R15, and R16 is separately and independently selected from the hydrogen atom, the halogen atom, the alkyl group, the aryl group, the alkoxy group, the hydroxy group, the ester group, the cyano group, the amino group, the thiol group, and the atom or the atomic group that can replace the foregoing group;
• and
• in Formula (2), p′ and q′ are integers greater than or equal to 0 and less than or equal to 6;
• x′ and y′ are integers greater than or equal to 0;
• p1′ and q1′ are integers greater than or equal to 0 and less than or equal to 6, and p1′ and q1′ are not 0 at the same time;
• R1′ to R12′, Ra′, Rb′, Rc′, and Rd′ are separately and independently selected from the hydrogen atom, the halogen atom, the alkyl group, the aryl group, the alkoxy group, the hydroxy group, the ester group, the cyano group, the amino group, the thiol group, and the atom or the atomic group that can replace the foregoing group;
• and R13′, R14′, R15′, and R16′ are separately and independently selected from the hydrogen atom, the halogen atom, the alkyl group, the aryl group, the alkoxy group, the hydroxy group, the ester group, the cyano group, the amino group, the thiol group, and the atom or the atomic group that can replace the foregoing group;
• or any two, three, or four of R13′, R14′, R15′, and R16′ are connected to form the cyclic structure, and a group that does not participate in forming the cyclic structure in R13′, R14′, R15′, and R16′ is separately and independently selected from the hydrogen atom, the halogen atom, the alkyl group, the aryl group, the alkoxy group, the hydroxy group, the ester group, the cyano group, the amino group, the thiol group, and the atom or the atomic group that can replace the foregoing group.

A device, comprising an optical product comprising a cyclic olefin polymer comprising:

• a repeat unit whose structural formula is shown in Formula (1) and a repeat unit whose structural formula is shown in Formula (2):
• wherein
• in Formula (1), p and q are integers greater than or equal to 0 and less than or equal to 6;
• x and y are integers greater than or equal to 0;
• p1 and q1 are integers greater than or equal to 0 and less than or equal to 6, and p1 and q1 are not 0 at the same time;
• R1 to R12, Ra, Rb, Rc, and Rd are separately and independently selected from a hydrogen atom, a halogen atom, an alkyl group, an aryl group, an alkoxy group, a hydroxy group, an ester group, a cyano group, an amino group, a thiol group, and an atom or an atomic group that can replace the foregoing group;
• and R13, R14, R15, and R16 are separately and independently selected from the hydrogen atom, the halogen atom, the alkyl group, the aryl group, the alkoxy group, the hydroxy group, the ester group, the cyano group, the amino group, the thiol group, and the atom or the atomic group that can replace the foregoing group;
• or any two, three, or four of R13, R14, R15, and R16 are connected to form a cyclic structure, and a group that does not participate in forming the cyclic structure in R13, R14, R15, and R16 is separately and independently selected from the hydrogen atom, the halogen atom, the alkyl group, the aryl group, the alkoxy group, the hydroxy group, the ester group, the cyano group, the amino group, the thiol group, and the atom or the atomic group that can replace the foregoing group;
• and
• in Formula (2), p′ and q′ are integers greater than or equal to 0 and less than or equal to 6;
• x′ and y′ are integers greater than or equal to 0;
• p1′ and q1′ are integers greater than or equal to 0 and less than or equal to 6, and p1′ and q1′ are not 0 at the same time;
• R1′ to R12′, Ra′, Rb′, Rc′, and Rd′ are separately and independently selected from the hydrogen atom, the halogen atom, the alkyl group, the aryl group, the alkoxy group, the hydroxy group, the ester group, the cyano group, the amino group, the thiol group, and the atom or the atomic group that can replace the foregoing group;
• and R13′, R14′, R15′, and R16′ are separately and independently selected from the hydrogen atom, the halogen atom, the alkyl group, the aryl group, the alkoxy group, the hydroxy group, the ester group, the cyano group, the amino group, the thiol group, and the atom or the atomic group that can replace the foregoing group;
• or any two, three, or four of R13′, R14′, R15′, and R16′ are connected to form the cyclic structure, and a group that does not participate in forming the cyclic structure in R13′, R14′, R15′, and R16′ is separately and independently selected from the hydrogen atom, the halogen atom, the alkyl group, the aryl group, the alkoxy group, the hydroxy group, the ester group, the cyano group, the amino group, the thiol group, and the atom or the atomic group that can replace the foregoing group.