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US 12,630,669 B2Granted
Waterborne epoxy curing agent
AssigneeEvonik Operations GmbH
InventorKeiji Wakita
Life of this patent
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Abstract
Provided is a waterborne epoxy curing agent comprising a reaction product of a) at least one amine having at least one moiety in the formula of -QNH—, wherein Q is a divalent hydrocarbon group, and wherein the amine has at least one tertiary amino group and at least one primary amino group per molecule; and b) at least one polyether polyol modified epoxide having one or more epoxide groups. Also provided is preparation methods thereof.
Claims8
A waterborne epoxy curing agent comprising a reaction product of:
- a) at least one amine having at least one moiety in the formula of -QNH—, wherein Q is a divalent hydrocarbon group, and wherein the amine has at least one tertiary amino group and at least one primary amino group per molecule, wherein the amine includes one or more compounds represented by formula (I):
- wherein n is an integer not less than 1, wherein R1 and R2 are independently a substituted or unsubstituted C1 to C16 alkyl, alkenyl, alkadienyl, cycloalkyl, cycloalkenyl, cycloalkadienyl, aryl, or aralkyl group, and wherein the amine is N,N-dimethylaminopropylamine, N,N-diethylaminopropylamine, N,N-dipropylaminopropylamine, N,N-dibutylaminopropylamine, N,N-dimethyldipropylenetriamine, N,N-diethyldipropylenetriamine, N3-[3-[(3-aminopropyl) amino]propyl]-N1,N1-dimethyl-1,3-propanediamine, or a mixture thereof;
- and
- b) at least one polyether polyol modified epoxide having one or more epoxide groups, wherein a stoichiometric ratio is in a range of 1 to 100, wherein the stoichiometric ratio is a ratio of an equivalent number in active amine hydrogen atoms of the amine to an equivalent number of epoxide groups in the polyether polyol modified epoxide.
1 more element
A method for preparing a waterborne epoxy curing agent comprising a reaction product of:
- a) at least one amine having at least one moiety in the formula of -QNH—, wherein Q is a divalent hydrocarbon group, and wherein the amine has at least one tertiary amino group and at least one primary amino group per molecule, wherein the amine includes one or more compounds represented by formula (I):
- wherein n is an integer not less than 1, wherein R1 and R2 are independently a substituted or unsubstituted C1 to C16 alkyl, alkenyl, alkadienyl, cycloalkyl, cycloalkenyl, cycloalkadienyl, aryl, or aralkyl group, and wherein the amine is N, N-dimethylaminopropylamine, N,N-diethylaminopropylamine, N,N-dipropylaminopropylamine, N,N-dibutylaminopropylamine, N,N-dimethyldipropylenetriamine, N,N-diethyldipropylenetriamine, N3-[3-[(3-aminopropyl) amino]propyl]-N1,N1-dimethyl-1,3-propanediamine, or a mixture thereof;
- and
- b) at least one polyether polyol modified epoxide having one or more epoxide groups, wherein a stoichiometric ratio of the amine to the epoxide is within a mole ratio of 1 to 100;
- and wherein the method comprises heating the reaction product to a temperature of 30° C. to 150° C. for 0.1 to 6 hours.
2 more elements
Dependencies are inferred from the claim text.