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US 12,629,667 B2Granted
Di-nitrogen ligands for supported coordinated platinum hydrosilylation catalysts
AssigneeThe Trustees of Indiana University
InventorsSteven L. Tait, Jr., Linxiao Chen
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Abstract
The invention describes metal catalysts such as Pt single-site centers on metal oxide supports, e.g., powdered supports, such as MgO, Al2O3, CeO2 or mixtures thereof with di-nitrogen containing ligands.
Claims7
A supported platinum catalyst comprising:
- (i) a di-nitrogen ligand,
- (ii) a support comprising MgO, and
- (iii) an anchoring ligand,
- wherein the di-nitrogen ligand is of formula (I):
- wherein R1 and R2 are each, independently, a C3 to a C12 branched or unbranched alkyl group, a substituted or unsubstituted phenyl group, or a carboxylic acid group;
- wherein the anchoring ligand is 2,2′-bipyridine-4,4′-dicarboxylic acid or 1,10-phenanthroline-5,6-dione;
- wherein the di-nitrogen ligand in (i) and the anchoring ligand in (iii) complex with a platinum metal ion;
- and
- wherein the anchoring ligand in (iii) is deposited on the support in (ii).
6 more elements
Dependencies are inferred from the claim text.