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US 12,624,135 B2Granted
Method for preparing super absorbent polymer
AssigneeLG Chem, Ltd.
InventorsSerin Lee, Seung Hun Yang, Ju Eun Kim, Joonil Cho, Hoyong Lee, Jungmin Lee
Life of this patent
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Abstract
This invention relates to a method for preparing super absorbent polymer, and more specifically, a method for preparing super absorbent polymer that can more productively prepare super absorbent polymer having excellent absorption properties and optimum gel strength at the same time, by using a specific polymerization initiator and chelating agent in combination during a crosslinking polymerization step.
Claims7
A method for preparing a super absorbent polymer comprising:
- conducting crosslinking polymerization of water soluble ethylenically unsaturated monomers having acid groups at least a part of which are neutralized with an internal crosslinking agent, in the presence of an azo-based polymerization initiator and diethylenetriamine pentaacetic acid, to obtain a hydrogel polymer;
- and
- drying, grinding and classifying the hydrogel polymer to form base resin powder,
- wherein the azo-based polymerization initiator and the diethylenetriamine pentaacetic acid are included at a weight ratio of 1:2 to 1:10, wherein the base resin powder has a centrifuge retention capacity (CRC) measured according to EDENA method WSP 241.2, of 45.0 g/g or more and wherein gel strength measured using tension and compression tester is 0.30 N or more, said gel strength being measured by dipping 2.5 g of the base resin powder in 50 g of a saline solution of ascorbic acid and swelling the base resin powder in a 40° C. oven for 24 hours, and then, measuring the swollen base resin powder.
1 more element
Dependencies are inferred from the claim text.