Removal of C3 lights from LPG feedstock to butane isomerization unit
AssigneeSabic Global Technologies B.V.
InventorsVijay Dinkar Bodas, Guillermo Leal Canelon, Mohammed Bismillah Ansari
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Abstract
Systems and methods for processing a C3 and C4 hydrocarbon mixture have been disclosed. The C3 and C4 hydrocarbon mixture is first processed in an isomerization unit to isomerize n-butane to form isobutane. The resulting effluent stream from the isomerization unit comprising primarily isobutane and C3 hydrocarbons, collectively, is flowed into a separation unit configured to separate the effluent stream to form a C3 stream comprising C1 to C3 hydrocarbons and a C4 stream comprising primarily isobutane. The isobutane in the C4 stream is further dehydrogenated to form isobutene, which is further flowed into an MTBE synthesis unit as a feedstock for producing MTBE.
Claims17
A method of processing a hydrocarbon mixture, the method comprising:
- processing a first hydrocarbon mixture comprising propane, n-butane, and isobutane in an isomerization unit at a temperature of 125 to 175° C. to isomerize the n-butane to produce isobutane;
- separating a mixture from the isomerization unit by a de-isobutanizer to produce and form an isomerization unit effluent comprising propane, isobutane, or combinations thereof and an unreacted n-butane stream;
- separating a second hydrocarbon mixture comprising propane, n-butane, and isobutane in a second separation unit to produce an overhead stream comprising primarily propane and isobutane, collectively, and a first C4 stream comprising n-butane;
- cracking the first C4 stream and/or the unreacted n-butane stream in a first steam cracking unit to produce propylene, ethylene, and benzene;
- combining the overhead stream and the isomerization unit effluent to form a combined stream;
- separating the combined stream to form a C3 stream comprising primarily propane and a second C4 stream comprising isobutane;
- dehydrogenating the isobutane of the second C4 stream in a dehydrogenation unit to produce isobutene in a dehydrogenation unit effluent;
- and
- reacting, in an etherification unit, the isobutene of the dehydrogenation unit effluent with an alkanol in the presence of a catalyst to produce an alkyl tert-butyl ether in a product stream.
Dependencies are inferred from the claim text.