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US 12,617,877 B2Granted
Metallocene supported catalyst and method for preparing olefine polymer using the same
AssigneeLG Chem, Ltd.
InventorsJinmyung Cha, Daesik Hong, Sangeun An, Seok Hwan Kim
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Abstract
Provided are a metallocene supported catalyst capable of greatly reducing generation of fine powder during preparation of olefin polymers while exhibiting excellent catalyst activity, and a method of preparing olefin polymers using the same.
Claims13
A metallocene supported catalyst comprising:
- a silica support comprising pores;
- a transition metal compound supported on the silica support;
- and
- nanosilica disposed on a surface of the silica support and has a mean particle size of 10 nm to 100 nm, wherein the mean particle size of the nanosilica is determined by a particle size at a point where a number-based cumulative distribution of particles according to a particle size reaches 50% when a particle size distribution is measured by a laser diffraction analysis, wherein a mean pore size of the pores in the silica support is smaller than the mean particle size of the nanosilica,
- wherein the transition metal compound is represented by the following Chemical Formula 1:
- in Chemical Formula 1,
- A is carbon, silicon, or germanium,
- X1 and X2 are each independently halogen,
- R1 and R2 are each independently C6-20 aryl unsubstituted or substituted with C1-20 alkyl,
- R2 to R4 and R6 to R8 are each independently hydrogen, halogen, C1-20 alkyl, C2-20 alkenyl, C1-20 alkylsilyl, C1-20 silylalkyl, C1-20 alkoxysilyl, C1-20 ether, C1-20 silylether, C1-20 alkoxy, C6-20 aryl, C7-20 alkylaryl, or C7-20 arylalkyl, and
- R9 and R10 are, the same as each other, C1-20 alkyl.
8 more elements
Dependencies are inferred from the claim text.