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US 12,617,760 B2Granted
[(5-phenyl-1-heteroaryl-1H-triazol-3-yl)oxy] acetic acid derivatives as safeners for the protection of useful plants and crop plants
AssigneeBayer Aktiengesellschaft
InventorsThomas Müller, Anna Maria Reingruber, Jens Frackenpohl, Hendrik Helmke, Jan Dittgen
Life of this patent
Estimating the term…
Abstract
The present invention relates to crop protection compounds and to compositions which comprise specific compounds as safeners for reducing phytotoxic effects of agrochemicals, especially herbicides. The invention relates more particularly to certain [5-(phenyl)-1-(heteroaryl)-1H-1,2,4-triazol-3-yl)oxy] acetic acid derivatives of the general formula (I) and their salts, to processes for preparing them and to their use as plant protection compounds (safeners).
Claims16
A compound of general formula (I) or salt thereof
- in which
- R1 is selected from hydrogen, halogen, cyano, nitro, (C1-C6)alkyl, (C2-C6)alkenyl, (C2-C6)alkynyl, (C3-C8)cycloalkyl, (C3-C8)cycloalkenyl, (C1-C6)alkoxy or (C1-C6)alkylS(O)p, wherein (C1-C6)alkyl, (C2-C6)alkenyl, (C2-C6)alkynyl, (C3-C8)cycloalkyl, (C3-C8)cycloalkenyl, (C1-C6)alkoxy and (C1-C6)alkylS(O)p are optionally substituted by one or more radicals selected from the group consisting of halogen, cyano, (C1-C6)alkoxy and (C1-C6)alkylS(O)p,
- R2 is heteroaryl, where the heteroaryl radical is unsubstituted or substituted by halogen, cyano, nitro, (C1-C6)alkyl, (C2-C6)alkenyl, (C2-C6)alkynyl, (C3-C8)cycloalkyl, (C3-C8)cycloalkenyl, (C1-C6)alkoxy or (C1-C6)alkylS(O)p, wherein (C1-C6)alkyl, (C2-C6)alkenyl, (C2-C6)alkynyl, (C3-C8)cycloalkyl, (C3-C8)cycloalkenyl, (C1-C6)alkoxy and (C1-C6)alkylS(O)p are optionally substituted by one or more radicals selected from the group consisting of halogen, cyano, (C1-C6)alkoxy and (C1-C6)alkylS(O)p,
- R3 is hydrogen or (C1-C6)alkyl,
- R4 is selected from hydrogen, (C1-C18)alkyl, (C1-C18)haloalkyl, (C1-C18)cyanoalkyl, (C2-C18)alkenyl, (C2-C18)alkynyl, (C3-C12)cycloalkyl, (C3-C12)cycloalkenyl, aryl, heteroaryl, (C1-C18)alkoxy-(C1-C18)alkyl, (C1-C18)haloalkoxy-(C1-C18)alkyl, (C1-C18)alkoxy-(C1-C18)haloalkyl, (C1-C18)alkylthio-(C1-C18)alkyl, (C1-C18)haloalkylthio-(C1-C18)alkyl, (C2-C18)haloalkenyl, (C2-C18)haloalkynyl, heterocyclyl-(C1-C18)alkyl, aryl-(C1-C18)alkyl, (C3-C12)cycloalkyl-(C1-C18)alkyl, (C1-C18)alkoxycarbonyl-(C1-C18)alkyl, and (C1-C18)alkoxycarbonyl-(C3-C12)cycloalkyl-(C1-C18)alkyl, or
- a radical of the formula —NRaRb or —N═CRcRd,
- wherein each of the Ra, Rb, Rc and Rd radicals is independently selected from hydrogen, (C1-C4)alkyl, (C2-C4)alkenyl, (C2-C4)alkynyl, benzyl, substituted benzyl, phenyl or substituted phenyl, or Ra and Rb together with the nitrogen atom may form a 3- to 8-membered heterocycle which may contain one or two ring heteroatoms from the group of N, O and S, but not in the case of a 3- or 4-membered heterocycle, and which is unsubstituted or substituted by one or more radicals from the group of (C1-C4)alkyl and (C1-C4)haloalkyl,
- or Rc and Rd together with the carbon atom are a 3- to 8-membered carbocyclic or heterocyclic radical which may contain 1 to 3 ring heteroatoms from the group of N, O and S, where the carbocyclic or heterocyclic radical is unsubstituted or substituted by one or more radicals from the group of (C1-C4)-alkyl and (C1-C4)-haloalkyl,
- n is a number from 0 to 5,
- and
- p is 0, 1 or 2.
8 more elements
Dependencies are inferred from the claim text.