Synthetic gypsum and gypsum boards produced therefrom
AssigneeUniversal Cement Corporation
InventorsFeng-Shuo Hsu, Chih-Yuan Hou
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Abstract
This invention discloses a synthetic gypsum and gypsum boards produced therefrom. Limestone (Calcium Carbonate), slaked lime (calcium hydroxide), water, and sulfuric acid are mixed, and alpha hemihydrate gypsum is optionally added as crystal seed to produce synthetic gypsum. The synthetic gypsum is then used to make gypsum boards. The gypsum board produced according to this invention contains at least 10% alpha hemihydrate gypsum.
Claims17
A process of producing synthetic gypsum, the process comprising:
- step 1 which comprises mixing Calcium Carbonate (CaCO3) and one of Calcium Hydroxide (Ca(OH)2) and Calcium Oxide (CaO) in a predetermined ratio, and adding water to form a suspension with a predetermined percentage of solid content;
- and
- step 2 which comprises adding sulfuric acid under normal pressure, and stirring the suspension and the added sulfuric acid,
- wherein during step 2, a temperature of the suspension rises, gas is generated, and gypsum is precipitated, and
- wherein synthetic gypsum is obtained after drying,
- wherein the synthetic gypsum, in a composition analysis according to ASTM-C471M standards, comprises:
- free water less than 10%, CaSO4·2H2O over 95%, particle size over 150 μm, and pH 5˜8,
- wherein in step 1, a predetermined amount of alpha-hemihydrate gypsum is added to the suspension as a crystal seed of dihydrate gypsum, and
- wherein the synthetic gypsum, in the composition analysis according to ASTM-C471M standards, further comprises:
- alpha-hemihydrate gypsum 20%˜80%.
A process of producing synthetic gypsum, the process comprising:
- step 1 which comprises mixing Calcium Carbonate (CaCO3) and one of Calcium Hydroxide (Ca(OH)2) and Calcium Oxide (CaO) in a ratio of 2:1˜8, with water to form a suspension with 20%˜40% solid content;
- step 2 which comprises adding a 20%˜60% sulfuric acid solution at normal pressure in a volume equivalent to 1˜1.5 times a molar amount of Calcium, and stirring and mixing the sulfuric acid solution with the suspension, wherein, during step 2, a temperature of a mixture of the sulfuric acid solution and the suspension continues to rise and gas is produced, until gas production stops, to obtain an intermediate product;
- and
- step 3 in which:
- the intermediate product is centrifuged to be dehydrated,
- the dehydrated intermediate product is mixed and stirred with water and a dilute sulfuric acid solution to obtain a product of pH of 3˜5,
- the product of the pH of 3˜5 is allowed to settle and precipitate,
- the settled and precipitated product is centrifuged to be dehydrated, and then washed with water, and
- the washed product is dried to produce synthetic gypsum.
A process of producing a gypsum board, comprising:
- step 1 which comprises mixing a predetermined ratio of Calcium Carbonate (CaCO3) and one of Calcium Hydroxide (Ca(OH)2) and Calcium Oxide (CaO), and adding water to form a suspension with a predetermined concentration of solid;
- step 2 which comprises adding a sulfuric acid solution of a predetermined concentration under normal pressure and in a volume equivalent to a predetermined multiple of a molar amount of Calcium, and stirring the sulfuric acid solution with the suspension, wherein, during step 2, a temperature of a mixture of the sulfuric acid solution and the suspension continues to rise and gas is generated, until the gas production stops, to obtain an intermediate product;
- step 3 in which:
- the intermediate product is centrifuged to be dehydrated,
- the dehydrated intermediate product is mixed with water and a dilute sulfuric acid solution to obtain a product of pH of 3˜5,
- the product of the pH of 3˜5 is allowed to settle,
- the settled product is centrifuged to be dehydrated, and then washed with water, and
- the washed product is dried to produce synthetic gypsum;
- step 4 which comprises:
- drying, grinding, and calcining the synthetic gypsum to produce 10˜50% alpha-hemihydrate calcium sulfate plaster powder, and then
- pulverizing and storing the alpha-hemihydrate calcium sulfate plaster powder;
- step 5 which comprises forming a gypsum slurry by mixing the alpha-hemihydrate calcium sulfate plaster powder, water, and auxiliary materials;
- and
- step 6 in which:
- the gypsum slurry is injected into a paper-lined mold, with a top or face paper and a bottom or back paper, to form continuous wet boards, and
- the wet boards are hardened, transferred, cut, dried, and trimmed to produce gypsum boards.
A process of producing a gypsum board, comprising:
- step 1 which comprises mixing Calcium Carbonate (CaCO3) with one of calcium hydroxide (Ca(OH)2) and calcium oxide (CaO) in a ratio of 2:1˜8, and adding water to form a suspension with a solid concentration of 20%˜40%;
- step 2 which comprises adding a 20%˜60% sulfuric acid solution at normal pressure in a volume equivalent to 1˜1.5 times a molar amount of calcium, and stirring and mixing the sulfuric acid solution with the suspension, wherein, during step 2, a temperature of a mixture of the sulfuric acid solution and the suspension rises and gas is generated, until gas production stops, to obtain an intermediate product;
- step 3 in which:
- the intermediate product is centrifuged to be dehydrated,
- the dehydrated intermediate product is mixed and stirred with water and a dilute sulfuric acid solution to obtain a product of pH of 3˜5,
- the product of the pH of 3˜5 is allowed to settle and precipitate,
- the settled and precipitated product is centrifuged to be dehydrated, and then washed with water, and
- the washed product is dried to produce synthetic gypsum;
- step 4 in which the synthetic gypsum is dried, ground, and calcined to produce a plaster powder containing 10˜50% alpha-hemihydrate calcium sulfate, which is then pulverized and stored;
- step 5 which comprises mixing the plaster powder, water, and auxiliary materials to form a gypsum slurry;
- and
- step 6 in which:
- the gypsum slurry is injected into a paper-lined mold, with a top or face paper and a bottom or back paper, to form continuous wet boards, and
- the wet boards are hardened, transferred, cut, dried, and trimmed to produce gypsum boards.
Dependencies are inferred from the claim text.