Organic electroluminescence device and electronic apparatus provided with the same

An organic electroluminescence device comprising

• a cathode,
• an anode, and
• an emitting layer disposed between the cathode and the anode, wherein
• the emitting layer comprises a compound represented by the following formula (1) and
• one or more compounds selected from the group consisting of a compound represented by the formula following (21), a compound represented by the formula following (31), a compound represented by the formula following (41), and a compound represented by the formula following (51):
• wherein in the formula (1),
• X1 is an oxygen atom or a sulfur atom;
• Ar1 is a substituted or unsubstituted aryl group including 6 to 50 ring carbon atoms, or
• a substituted or unsubstituted monovalent heterocyclic group including 5 to 50 ring atoms;
• L1 is a single bond,
• a substituted or unsubstituted arylene group including 6 to 50 ring carbon atoms, or
• a substituted or unsubstituted divalent heterocyclic group including 5 to 50 ring atoms;
• R1 to R8 and R11 to R19 are independently
• a hydrogen atom, a halogen atom, a cyano group, a nitro group,
• a substituted or unsubstituted alkyl group including 1 to 50 carbon atoms,
• a substituted or unsubstituted alkenyl group including 2 to 50 carbon atoms,
• a substituted or unsubstituted alkynyl group including 2 to 50 carbon atoms,
• a substituted or unsubstituted cycloalkyl group including 3 to 50 ring carbon atoms,
• —Si(R901)(R902)(R903),
• —O—(R904),
• —S—(R905),
• —N(R906)(R907),
• a substituted or unsubstituted aryl group including 6 to 50 ring carbon atoms, or
• a substituted or unsubstituted monovalent heterocyclic group including 5 to 50 ring atoms;
• R901 to R907 are independently
• a hydrogen atom,
• a substituted or unsubstituted alkyl group including 1 to 50 carbon atoms,
• a substituted or unsubstituted cycloalkyl group including 3 to 50 ring carbon atoms,
• a substituted or unsubstituted aryl group including 6 to 50 ring carbon atoms, or
• a substituted or unsubstituted monovalent heterocyclic group including 5 to 50 ring atoms;
• when two or more of each of R901 to R907 are present, the two or more of each of R901 to R907 are the same or different;
• wherein in the formula (21),
• Zs are independently CRa or N;
• A1 ring and A2 ring are independently a substituted or unsubstituted aromatic hydrocarbon ring including 6 to 50 ring carbon atoms, or a substituted or unsubstituted heterocyclic ring including 5 to 50 ring atoms;
• when plural Ras exist, one or more sets of two or more adjacent groups of Ra are bonded with each other to form a substituted or unsubstituted, saturated or unsaturated ring, or do not form a substituted or unsubstituted, saturated or unsaturated ring;
• when plural Rbs exist, one or more sets of two or more adjacent groups of Rb are bonded with each other to form a substituted or unsubstituted, saturated or unsaturated ring, or do not form a substituted or unsubstituted, saturated or unsaturated ring;
• when plural Rcs exist, one or more sets of two or more adjacent groups of Rc are bonded with each other to form a substituted or unsubstituted, saturated or unsaturated ring, or do not form a substituted or unsubstituted, saturated or unsaturated ring;
• n21 and n22 are independently an integer of 0 to 4;
• Ra to Rc that do not form the substituted or unsubstituted, saturated or unsaturated ring are independently
• a substituted or unsubstituted alkyl group including 1 to 50 carbon atoms,
• a substituted or unsubstituted alkenyl group including 2 to 50 carbon atoms,
• a substituted or unsubstituted alkynyl group including 2 to 50 carbon atoms,
• a substituted or unsubstituted cycloalkyl group including 3 to 50 ring carbon atoms,
• —Si(R901)(R902)(R903),
• —O—(R904),
• —S—(R905),
• —N(R906)(R907),
• a halogen atom, a cyano group, a nitro group,
• a substituted or unsubstituted aryl group including 6 to 50 ring carbon atoms, or
• a substituted or unsubstituted monovalent heterocyclic group including 5 to 50 ring atoms;
• and
• R901 to R907 are as defined in the formula (1);
• wherein in the formula (31),
• one or more sets of two or more adjacent groups of R301 to R307 and R311 to R317 form a substituted or unsubstituted, saturated or unsaturated ring, or do not form a substituted or unsubstituted, saturated or unsaturated ring;
• R301 to R307 and R311 to R317 that do not form the substituted or unsubstituted, saturated or unsaturated ring are independently
• a hydrogen atom,
• a substituted or unsubstituted alkyl group including 1 to 50 carbon atoms,
• a substituted or unsubstituted alkenyl group including 2 to 50 carbon atoms,
• a substituted or unsubstituted alkynyl group including 2 to 50 carbon atoms,
• a substituted or unsubstituted cycloalkyl group including 3 to 50 ring carbon atoms,
• —Si(R901)(R902)(R903),
• —O—(R904),
• —S—(R905),
• —N(R906)(R907),
• a halogen atom, a cyano group, a nitro group,
• a substituted or unsubstituted aryl group including 6 to 50 ring carbon atoms, or
• a substituted or unsubstituted monovalent heterocyclic group including 5 to 50 ring atoms;
• R321 and R322 are independently
• a hydrogen atom,
• a substituted or unsubstituted alkyl group including 1 to 50 carbon atoms,
• a substituted or unsubstituted alkenyl group including 2 to 50 carbon atoms,
• a substituted or unsubstituted alkynyl group including 2 to 50 carbon atoms,
• a substituted or unsubstituted cycloalkyl group including 3 to 50 ring carbon atoms,
• —Si(R901)(R902)(R903),
• —O—(R904),
• —S—(R905),
• —N(R906)(R907),
• a halogen atom, a cyano group, a nitro group,
• a substituted or unsubstituted aryl group including 6 to 50 ring carbon atoms, or
• a substituted or unsubstituted monovalent heterocyclic group including 5 to 50 ring atoms;
• and
• R901 to R907 are as defined in the formula (1);
• wherein in the formula (41),
• a ring, b ring and c ring are independently
• a substituted or unsubstituted aromatic hydrocarbon ring including 6 to 50 ring carbon atoms, or
• a substituted or unsubstituted heterocyclic ring including 5 to 50 ring atoms;
• R401 and R402 are independently bonded to the a ring, the b ring or the c ring to form a substituted or unsubstituted heterocyclic ring or do not form a substituted or unsubstituted heterocyclic ring;
• R401 and R402 that do not form the substituted or unsubstituted heterocyclic ring are independently
• a substituted or unsubstituted alkyl group including 1 to 50 carbon atoms,
• a substituted or unsubstituted alkenyl group including 2 to 50 carbon atoms,
• a substituted or unsubstituted alkynyl group including 2 to 50 carbon atoms,
• a substituted or unsubstituted cycloalkyl group including 3 to 50 ring carbon atoms,
• a substituted or unsubstituted aryl group including 6 to 50 ring carbon atoms, or
• a substituted or unsubstituted monovalent heterocyclic group including 5 to 50 ring atoms;
• wherein in the formula (51),
• r ring is a ring represented by the formula (52) or formula (53) which is fused to an adjacent ring at an arbitrary position;
• q ring and s ring are independently a ring represented by the formula (54) which is fused to an adjacent ring at an arbitrary position;
• p ring and t ring are independently a ring represented by the formula (55) or the formula (56) which is fused to an adjacent ring at an arbitrary position;
• when plural R501's exist, adjacent plural R501's are bonded with each other to form a substituted or unsubstituted, saturated or unsaturated ring, or do not form a substituted or unsubstituted, saturated or unsaturated ring;
• X501 is an oxygen atom, a sulfur atom, or NR502;
• R501 and R502 that do not form the substituted or unsubstituted saturated or unsaturated ring are
• a substituted or unsubstituted alkyl group including 1 to 50 carbon atoms,
• a substituted or unsubstituted alkenyl group including 2 to 50 carbon atoms,
• a substituted or unsubstituted alkynyl group including 2 to 50 carbon atoms,
• a substituted or unsubstituted cycloalkyl group including 3 to 50 ring carbon atoms,
• —Si(R901)(R902)(R903),
• —O—(R904),
• —S—(R905),
• —N(R906)(R907),
• a halogen atom, a cyano group, a nitro group,
• a substituted or unsubstituted aryl group including 6 to 50 ring carbon atoms, or
• a substituted or unsubstituted monovalent heterocyclic group including 5 to 50 ring atoms;
• R901 to R907 are as defined in the formula (1);
• Ar501 and Ar502 are independently
• a substituted or unsubstituted alkyl group including 1 to 50 carbon atoms,
• a substituted or unsubstituted alkenyl group including 2 to 50 carbon atoms,
• a substituted or unsubstituted alkynyl group including 2 to 50 carbon atoms,
• a substituted or unsubstituted cycloalkyl group including 3 to 50 ring carbon atoms,
• a substituted or unsubstituted aryl group including 6 to 50 ring carbon atoms, or
• a substituted or unsubstituted monovalent heterocyclic group including 5 to 50 ring atoms;
• L501 is
• a substituted or unsubstituted alkylene group including 1 to 50 carbon atoms,
• a substituted or unsubstituted alkenylene group including 2 to 50 carbon atoms,
• a substituted or unsubstituted alkynylene group including 2 to 50 carbon atoms,
• a substituted or unsubstituted cycloalkylene group including 3 to 50 ring carbon atoms,
• a substituted or unsubstituted arylene group including 6 to 50 ring carbon atoms, or
• a substituted or unsubstituted divalent heterocyclic group including 5 to 50 ring atoms;
• m1 is an integer of 0 to 2, m2 is an integer of 0 to 4, m3 is independently an integer of 0 to 3, and m4 is independently an integer of 0 to 5;
• when plural R501's exist, the plural R501's may be the same or different.