Catalytic cracking additive, preparation method therefor, and application thereof
AssigneesChina Petroleum & Chemical Corporation, Research Institute of Petroleum Processing, Sinopec
InventorsShanqing Yu, Jiasong Yan, Jiexiao Zhang, Wei Lin
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Abstract
A catalytic cracking additive, its preparation and application thereof are provided. The catalytic cracking additive contains 10-50 wt % of a modified β zeolite, 20-85 wt % of a clay and 5-35 wt % of a boron-containing binder, based on the total weight of the catalytic cracking additive. The modified β zeolite comprises 0.1-1 wt % of CuO and 1-15 wt % of P2O5, and has a micro-activity index of at least 58; the boron-containing binder comprises 70-97 wt % of Al2O3 and 3-30 wt % of B2O3, and has a pH value of 1.0-3.5. The catalytic cracking additive can significantly improve the yield of C4 olefins and the concentration of C4 olefins in liquefied gas.
Claims19
A catalytic cracking additive, comprising 10-50 wt % of a modified β zeolite, 20-85 wt % of a clay, and 5-35 wt % of a boron-containing binder, based on the total weight of the catalytic cracking additive, wherein:
- the modified β zeolite is the only zeolite present in the catalytic cracking additive and comprises 0.1-1 wt % of CuO and 1-15 wt % of P2O5, and has a micro-activity index of at least 58;
- and the boron-containing binder comprises 70-97 wt % of Al2O3 and 3-30 wt % of B2O3, and has a pH value of 1.0-3.5,
- wherein the catalytic cracking additive is prepared by a method comprising the steps of:
- S1:
- mixing a B zeolite, a phosphorus source, a copper source and a first solvent, and adjusting the pH value of the mixture to 1.0-6.0 to form a slurry;
- S2:
- mixing an aluminum source, a boron source, an acid and a second solvent to obtain the boron-containing binder, the aluminum source being the sole alumina source for the catalytic cracking additive and is selected from pseudo-boehmite, alumina, aluminum hydroxide, boehmite, and combinations thereof, and
- S3:
- mixing the boron-containing binder, the slurry, a clay and a third solvent, and drying the resulting mixture and calcining the dried mixture at 300-650° C. to obtain the catalytic cracking additive.
Dependencies are inferred from the claim text.