Cationic curing agent, method for producing same and cationically curable composition
AssigneeDexerials Corporation
InventorsTakeshi Nishio, Shunsuke Tsuda, Kazunobu Kamiya
Life of this patent
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Abstract
Provided is a cationic curing agent including porous particles and a mixture carried on the porous particles. The mixture includes a compound represented by Formula (1) below in which R1 to R3 are identical and R1 to R6 are identical and a compound represented by Formula (1) below in which at least one of R1 to R6 is different. In Formula (1), R1 to R3 are each an optionally branched alkyl group having from 1 to 18 carbon atoms, or a phenyl group that may have a substituent, and R4 to R6 are each a hydrogen atom, an optionally branched alkyl group having from 1 to 4 carbon atoms, a halogenoalkyl group, an alkoxy group, or a phenoxy group that may have a substituent.
Claims13
A cationic curing agent, comprising:
- porous particles;
- and
- a mixture carried on the porous particles, the mixture including a first compound and a second compound,
- the first compound being represented by Formula (1) below:
- in which
- R1 to R3 are identical, and
- R4 to R6 are identical;
- and
- the second compound being represented by Formula (1) in which at least one of R1 to R6 is different, wherein in Formula (1),
- R1 to R3 are each an optionally branched alkyl group having from 1 to 18 carbon atoms, or a phenyl group that may have a substituent, and
- R4 to R6 are each a hydrogen atom, an optionally branched alkyl group having from 1 to 4 carbon atoms, a halogenoalkyl group, an alkoxy group, or a phenoxy group that may have a substituent,
- wherein surfaces of the porous particles include a reaction product of dimethyl(dimethoxy)silane, cyclohexyl(dimethoxy)methylsilane, or trimethylmethoxysilane.
A cationic curing agent, comprising:
- porous particles;
- and
- a mixture carried on the porous particles, the mixture including a first compound, a second compound, and a third compound,
- the first compound being represented by Formula (1) below:
- in which
- R1 to R3 are identical, and
- R4 to R6 are identical;
- the second compound being represented by Formula (1) in which at least one of R1 to R6 is different, wherein in Formula (1),
- R1 to R3 are each an optionally branched alkyl group having from 1 to 18 carbon atoms, or a phenyl group that may have a substituent, and
- R4 to R6 are each a hydrogen atom, an optionally branched alkyl group having from 1 to 4 carbon atoms, a halogenoalkyl group, an alkoxy group, or a phenoxy group that may have a substituent;
- and
- the third compound being represented by Formula (2) below:
- in which
- Z is a hydrogen atom or an electron attractive group, and a is an integer of from 0 to 5,
- wherein surfaces of the porous particles include a reaction product of dimethyl(dimethoxy)silane, cyclohexyl(dimethoxy)methylsilane, or trimethylmethoxysilane.
A method for producing a cationic curing agent, the method comprising:
- dispersing a first compound, a second compound, and porous particles in an organic solvent,
- the first compound being a compound represented by Formula (1) below:
- in which
- R1 to R3 are identical, and
- R4 to R6 are identical;
- and
- the second compound being represented by Formula (1) in which at least one of R1 to R6 is different, wherein in Formula (1),
- R1 to R3 are each an optionally branched alkyl group having from 1 to 18 carbon atoms, or a phenyl group that may have a substituent, and
- R4 to R6 are each a hydrogen atom, an optionally branched alkyl group having from 1 to 4 carbon atoms, a halogenoalkyl group, an alkoxy group, or a phenoxy group that may have a substituent;
- removing, after the dispersing, the solvent to produce the porous particles carrying a mixture that includes the first compound represented by Formula (1) in which R1 to R3 are identical and R4 to R6 are identical and the second compound represented by Formula (1) in which at least one of R1 to R6 is different;
- and
- forming a reaction product of dimethyl(dimethoxy)silane, cyclohexyl(dimethoxy)methylsilane, or trimethylmethoxysilane on surfaces of the porous particles.
A method for producing a cationic curing agent, the method comprising:
- dispersing a first compound, a second compound, a third compound, and porous particles in an organic solvent,
- the first compound being represented by Formula (1) below:
- in which
- R1 to R3 are identical, and
- R4 to R6 are identical;
- the second compound being represented by Formula (1) in which at least one of R1 to R6 is different, wherein in Formula (1),
- R1 to R3 are each an optionally branched alkyl group having from 1 to 18 carbon atoms, or a phenyl group that may have a substituent, and
- R4 to R6 are each a hydrogen atom, an optionally branched alkyl group having from 1 to 4 carbon atoms, a halogenoalkyl group, an alkoxy group, or a phenoxy group that may have a substituent;
- and
- the third compound being represented by Formula (2) below:
- in which
- Z is a hydrogen atom or an electron attractive group, and a is an integer of from 0 to 5;
- removing, after the dispersing, the solvent to produce the porous particles carrying a mixture that includes the first compound represented by Formula (1) in which R1 to R3 are identical and R4 to R6 are identical, the second compound represented by Formula (1) in which at least one of R1 to R6 is different, and the third compound represented by Formula (2);
- and
- forming a reaction product of dimethyl(dimethoxy)silane, cyclohexyl(dimethoxy)methylsilane, or trimethylmethoxysilane on surfaces of the porous particles.
Dependencies are inferred from the claim text.