Polyvinyl alcohol-based resin, method for producing polyvinyl alcohol-based resin, dispersant and dispersant for suspension polymerization
AssigneeMitsubishi Chemical Corporation
InventorsYoshihito Yamauchi, Takenori Shige, Tadashi Murakami
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Abstract
An object of the present invention is to provide a PVA-based resin having a degree of saponification obtained in the middle stage of the reaction, that is, an average degree of saponification of 68 mol % to 85 mol %, a narrow degree of saponification distribution, and excellent dispersion stability. The present invention relates to a polyvinyl alcohol-based resin having an average degree of saponification of 68 mol % to 85 mol %, and a ¼ value width of 7.0 minutes or less in a degree of saponification distribution obtained by high performance liquid chromatogram measured under specific conditions.
Claims3
A polyvinyl alcohol-based resin, wherein
- a volume average degree of saponification is 68 mol % to 85 mol %, and
- a ¼ value width of a degree of saponification distribution obtained by high performance liquid chromatogram measured is 7.0 minutes or less under the following conditions:
- apparatus:
- liquid chromatography,
- detector:
- corona charged aerosol detector,
- column:
- particle diameter:
- 5 μm, 4.6 mm inner diameter×250 mm length,
- mobile phase flow rate:
- 0.5 mL/min,
- injection amount:
- 50 μL, eluent:
- solvent A ultrapure water, solvent B tetrahydrofuran,
- high-pressure gradient:
- solvent A/solvent B volume ratio=90/10 at 0 minutes, 90/10 at 5 minutes, 14/86 at 43 minutes, and 14/86 at 58 minutes by a gradient elution method,
- measurement temperature:
- 50° C.,
- sample:
- 10 vol % tetrahydrofuran aqueous solution at concentration:
- 2 mg/mL, and
- data acquisition interval:
- every second.
Dependencies are inferred from the claim text.