Zirconia powder, zirconia sintered body, and method for producing zirconia sintered body
AssigneeDaiichi Kigenso Kagaku Kogyo Co., Ltd.
InventorMasayuki Takai
Life of this patent
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Abstract
A zirconia powder in which when a stabilizer is Y2O3, a content thereof is 1.4 mol % or more and less than 2.0 mol %; when the stabilizer is Er2O3, a content thereof is 1.4 mol % or more and 1.8 mol % or less; when the stabilizer is Yb2O3, a content thereof is 1.4 mol % or more and 1.8 mol % or less; and when the stabilizer is CaO, a content thereof is 3.5 mol % or more and 4.5 mol % or less; and in a range of 10 nm or more and 200 nm or less in a pore distribution, a peak top diameter of a pore volume distribution is 20 nm or more and 120 nm or less, a pore volume is 0.2 ml/g or more and less than 0.5 ml/g, and a pore distribution width is 30 nm or more and 170 nm or less.
Claims19
A zirconia powder comprising a stabilizer, wherein
- the stabilizer is CaO, Y2O3, Er2O3, or Yb2O3,
- when the stabilizer is Y2O3, a content of the Y2O3 based on an entire amount of the zirconia powder is 1.4 mol % or more and less than 2.0 mol %,
- when the stabilizer is Er2O3, a content of the Er2O3 based on an entire amount of the zirconia powder is 1.4 mol % or more and 1.8 mol % or less,
- when the stabilizer is Yb2O3, a content of the Yb2O3 based on an entire amount of the zirconia powder is 1.4 mol % or more and 1.8 mol % or less, and
- when the stabilizer is CaO, a content of the CaO based on an entire amount of the zirconia powder is 3.5 mol % or more and 4.5 mol % or less,
- in a range of 10 nm or more and 200 nm or less in a pore distribution based on a mercury intrusion method, a peak top diameter in a pore volume distribution is 20 nm or more and 120 nm or less, a pore volume is 0.2 ml/g or more and less than 0.5 ml/g, and a pore distribution width is 30 nm or more and 170 nm or less, and
- the zirconia powder includes a property of, upon being sintered under conditions at 1200° C. or higher and 1350° C. or lower and for 1 hour or more and 5 hours or less, producing a zirconia sintered body wherein a ratio of a monoclinic crystal phase contained in a crystal phase is 0.2% or more and 2.9% or less.
A zirconia sintered body, comprising
- a stabilizer,
- wherein the stabilizer is one or more compounds selected from the group consisting of CaO, Y2O3, Er2O3, and Yb2O3,
- when the stabilizer is only Y2O3, a content of the Y2O3 based on an entire amount of a zirconia powder used to make the zirconia sintered body is 1.4 mol % or more and less than 1.8 mol %,
- when the stabilizer is only Er2O3, a content of the Er2O3 based on an entire amount of a zirconia powder used to make the zirconia sintered body is 1.4 mol % or more and 1.8 mol % or less,
- when the stabilizer is only Yb2O3, a content of the Yb2O3 based on an entire amount of a zirconia powder used to make the zirconia sintered body is 1.4 mol % or more and 1.8 mol % or less, and
- when the stabilizer is only CaO, a content of the CaO based on an entire amount of a zirconia powder used to make the zirconia sintered body zirconia powder is 3.5 mol % or more and 4.5 mol % or less, and
- a ratio of a monoclinic crystal phase contained in a crystal phase is 0.2% or more and 2.9% or less,
- a length of a crack generated in the sintered body when a load is set to 50 kgf in toughness measurement by an IF method is 1 μm or more and 90 μm or less, and
- a three-point bending strength is 80 kg/mm2 or more and 150 kg/mm2 or less.
Dependencies are inferred from the claim text.