CuWO4 hollow nanosphere and methods of making thereof
AssigneeCity University of Hong Kong
InventorsJohnny Chung Yin Ho, Dong Chen, Shaoce Zhang, Xiuming Bu, Quan Quan
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Abstract
Electrochemical conversion of nitrate to ammonia is an approach to alleviate nitrate pollution in water and simultaneously generate green NH3 fuels. The practical application of this approach is challenging due to the lack of efficient electrocatalysts. The present disclosure relates generally to an electrocatalyst including a plurality of CuWO4 hollow nanospheres, which include asymmetric oxygen vacancies and adjacent Mo clusters, and methods of making and using the same. The electrocatalyst of the present disclosure is designed for efficient ammonia electrosynthesis.
Claims17
A catalyst comprising:
- a CuWO4 hollow nanosphere;
- asymmetric oxygen vacancies within the CuWO4 hollow nanosphere;
- Mo clusters within the CuWO4 hollow nanosphere, wherein the Mo clusters are adjacent to the asymmetric oxygen vacancies;
- and
- wherein the catalyst exhibits one or both of (i) a NH3 Faradaic efficiency of 94.60±3.75% and (ii) a yield rate of about 5.84±0.45 mg h−1 mgcat.−1 at −0.7 V versus RHE.
Dependencies are inferred from the claim text.