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US 12,606,766 B2Granted
Multipurpose oxypyridinones and their functional use-4
AssigneeInfineum International Limited
InventorsDavid R. Coultas, Joanne Tory, Abby Casey
Life of this patent
Estimating the term…
Abstract
A composition is provided to comprise a non-aqueous medium and a 3,4-oxypyridine compound of structure (I): with each A being oxygen and/or sulfur, and with a variety of substituents at R1-R5 to enable a solution or an at least semi-stable emulsion to be formed in the non-aqueous medium. Methods of use are included herein, which may be focused on situations where the composition can be used as a lubricant and/or coolant.
Claims18
A lubricant composition comprising:
- a Group I, Group II, Group III, Group IV, and/or Group V lubricating oil basestock;
- a compound of structure (I):
- wherein:
- each A is individually an oxygen atom, a sulfur atom, an oxymethyl (—CH2—O—) moiety, or a methylthio (—CH2—S—) moiety;
- R1 is hydrogen;
- an ammonium ion;
- a C1-C6 monoalkylammonium ion;
- a C1-C6 dialkylammonium ion;
- a C1-C6 trialkylammonium ion;
- a C1-C6 tetraalkylammonium ion;
- a C1-C6 monoalkylsilyl moiety;
- a C1-C6 dialkylsilyl moiety;
- a C1-C6 trialkylsilyl moiety;
- an optionally substituted aryl, alkyl, alkaryl, or aralkyl sulfonyl moiety;
- a linear, branched, and/or cyclic C1-C20 hydrocarbyl sulfide;
- a linear, branched, and/or cyclic C1-C20 hydrocarbyl moiety;
- an at least partially halogenated linear, branched, and/or cyclic C1-C20 moiety;
- an ether-containing linear, branched, and/or cyclic C1-C20 moiety;
- a thioether-containing linear, branched, and/or cyclic C1-C20 moiety;
- an ester-containing linear, branched, and/or cyclic C1-C20 moiety;
- a thioester-containing linear, branched, and/or cyclic C1-C20 moiety;
- a linear, branched, and/or cyclic C1-C20 acyl moiety;
- a linear, branched, and/or cyclic C1-C20 thioacyl moiety;
- a linear, branched, and/or cyclic C1-C20 hydrocarbyloxyacyl moiety;
- a linear, branched, and/or cyclic C1-C20 hydrocarbyloxythioacyl moiety;
- a linear, branched, and/or cyclic C1-C20 hydrocarbylthiocarbonyl moiety;
- a linear, branched, and/or cyclic C1-C20 hydrocarbylthio-thioacyl moiety;
- an amide-containing linear, branched, and/or cyclic C1-C20 moiety;
- a thioamide-containing linear, branched, and/or cyclic C1-C20 moiety;
- a ketone-containing linear, branched, and/or cyclic C1-C20 moiety;
- a thioketone-containing linear, branched, and/or cyclic C1-C20 moiety;
- an aldehyde-containing linear, branched, and/or cyclic C1-C20 moiety;
- a thioaldehyde-containing linear, branched, and/or cyclic C1-C20 moiety;
- a mercaptan-containing linear, branched, and/or cyclic C1-C20 moiety;
- a hydroxyl-containing linear, branched, and/or cyclic C1-C20 moiety;
- a nonionic linear, branched, and/or (hetero) cyclic moiety containing 1 to 20 carbon atoms at least one nitrogen atom, and optionally at least one sulfur and/or oxygen atom;
- or another compound of structure (I) connected as an ether or thioether at a meta position to the ring nitrogen thereof;
- R2 is hydrogen;
- a halogen;
- a linear, branched, and/or cyclic C1-C12 hydrocarbyl moiety;
- an at least partially halogenated linear, branched, and/or cyclic C1-C12 moiety;
- an amine-containing linear, branched, and/or cyclic C1-C20 moiety;
- an ether-containing linear, branched, and/or cyclic C1-C20 moiety;
- a hydroxyl-containing linear, branched, and/or cyclic C1-C12 moiety;
- an aldehyde-containing linear, branched, and/or cyclic C1-C20 moiety;
- or a nitrile-containing linear, branched, and/or cyclic C1-C20 moiety;
- R3 is hydrogen;
- a halogen;
- or a linear, branched, and/or cyclic C6-C24 hydrocarbyl moiety;
- R4 is hydrogen;
- a halogen;
- a linear, branched, and/or cyclic C1-C12 hydrocarbyl moiety;
- an at least partially halogenated linear, branched, and/or cyclic C1-C12 moiety;
- an amine-containing linear, branched, and/or cyclic C1-C20 moiety;
- an ether-containing linear, branched, and/or cyclic C1-C20 moiety;
- a hydroxyl-containing linear, branched, and/or cyclic C1-C12 moiety;
- an aldehyde-containing linear, branched, and/or cyclic C1-C20 moiety;
- or a nitrile-containing linear, branched, and/or cyclic C1-C20 moiety;
- and
- R5 is hydrogen;
- a halogen;
- a linear, branched, and/or cyclic C1-C12 hydrocarbyl moiety;
- an at least partially halogenated linear, branched, and/or cyclic C1-C12 moiety;
- a hydroxylated linear, branched, and/or cyclic C1-C6 moiety;
- or an R1-A-moiety;
- or alternatively one or more of R1 and R2, R2 and R3, R3 and R4, and R4 and R5 may together form one or more (hetero) cyclic rings;
- with the proviso that R1 and R3 are not both hydrogen;
- and
- either:
- an optionally substituted triazole corrosion inhibitor, an optionally substituted benzotriazole corrosion inhibitor, an optionally substituted thiadiazole, an optionally substituted thiadiazole corrosion inhibitor, an ashless dihydrocarbyl dithiocarbamate, a C8-C18 acrylate, a C2-C6 dialkylene glycol diester, a tri-hydrocarbyl C1-C8 borate corrosion inhibitor, or a combination thereof;
- or
- substantially none of the following:
- an optionally substituted triazole corrosion inhibitor;
- an optionally substituted benzotriazole corrosion inhibitor;
- an optionally substituted thiadiazole corrosion inhibitor;
- an ashless dihydrocarbyl dithiocarbamate;
- a C8-C18 acrylate;
- a C2-C6 dialkylene glycol diester;
- and a tri-hydrocarbyl C1-C8 borate corrosion inhibitor;
- and
- at least one additional lubricant additive selected from the group consisting of a calcium- and/or magnesium-containing detergent, an ashless dispersant, an additional corrosion inhibitor, an antioxidant, a friction modifier, an antiwear agent, an antifoamant, a viscosity modifier, a pour point depressant, a tackifier, a demulsifier, an extreme pressure agent, a seal swell agent, and a combination thereof.
78 more elements
Dependencies are inferred from the claim text.