Segmented silicone polymers and methods of making and using the same

A siloxane polymer comprising:

• (a) one or more segments of formula (1):
• and
• (b) one or more segments of formula (II):
• wherein:
• each R1, R2, R3, and R4 is independently a hydrogen atom, a C1-14 hydrocarbyl group, or a C1-14 hydrocarbyloxy group, wherein at least one of R1, R2, R3, and R4 is a hydrogen atom;
• each X1 and X2 is independently an oxygen atom, a sulfur atom, >NH, or >N(C1-6 alkyl);
• each G1 and G2 is independently a C1-14 hydrocarbylene group;
• each G3 is independently a C1-14 hydrocarbylene group, which is optionally substituted one or more times by substituents selected from the group consisting of —OH and —O(C1-6alkyl);
• and
• each k is independently an integer ranging from 5 to 5000,
• wherein the segments of formula (I) and the segments of formula (II) together make up at least 60% by weight of the siloxane polymer;
• and
• wherein the numerical ratio of segments of formula (I) to segments of formula (II) in the siloxane polymer ranges from 1:5 to 5:1.