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US 12,605,794 B2Granted
Flux and solder paste
AssigneeSenju Metal Industry Co., Ltd.
InventorsMutsuki Kaneko, Ryuichi Tsuda, Kazuyori Takagi
Life of this patent
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Abstract
The present invention employs a flux containing a resin component, an activator, and a solvent. The resin component contains a copolymer (A) having an alkene-derived repeating unit (a1), and an acrylic acid-derived repeating unit (a2) in which a hydrogen atom bonded to a carbon atom at an α-position may be substituted with a substituent, and contains a rosin (B). A mixing ratio of the copolymer (A) and the rosin (B) is 1 or more as a mass ratio represented by copolymer (A)/rosin (B).
Claims12
A solder paste comprising:
- a solder alloy powder and a flux,
- wherein the flux comprising:
- a resin component;
- an activator;
- and
- a solvent,
- wherein the resin component contains
- a copolymer (A) having an alkene-derived repeating unit (a1), and an acrylic acid-derived repeating unit (a2) in which a hydrogen atom bonded to a carbon atom at an α-position may be substituted with a substituent, and
- a rosin (B),
- a mixing ratio of the copolymer (A) and the rosin (B) is 2 or more as a mass ratio represented by copolymer (A)/rosin (B),
- regarding the solder paste, an evaluation of temperature cycle reliability is A, and
- regarding the solder paste, an evaluation of solder paste separation prevention ability is A or B,
- wherein the evaluation of the temperature cycle reliability is determined by preparing a printed circuit board,
- regarding the printed circuit board, thickness is 1.0 mm, land dimension is 1.5 mm×0.25 mm, pitch is 0.5 mm, width between lands is 0.25 mm, number of the lands is 64,
- printing the solder paste on the printed circuit board using a metal mask having a thickness of 150 μm,
- obtaining a test board by performing reflow soldering to the printed circuit board after printing the solder paste,
- in the reflow profile, the pre-heating is performed at 150° C. to 180° C. for 90 seconds, the peak temperature is 240° C., and the solder melting time is 40 seconds,
- the reflow is performed in a nitrogen atmosphere, and the oxygen concentration is 1,000 ppm or less,
- putting the obtained test board in a heat cycle tester and subjecting the obtained test board to 3,000 cycles with standing at a low temperature of −40° C. and at a high temperature of 125° C. as one cycle,
- the standing times at the low temperature and the high temperature are both 30 minutes, and the time for one cycle is set to 70 minutes,
- observing cracking of the flux residue after performing 3,000 cycles, and
- evaluating the temperature cycle reliability as A when no cracks are confirmed at any point,
- wherein the evaluation of the solder paste separation prevention ability is determined by putting 500 g of the solder paste in a container and left to stand in a constant-temperature tank at 40° C. for 3 days,
- after a lapse of the following predetermined time, visually observing the solder paste to determine whether or not the solder paste is separated according to the following criteria,
- evaluating the solder paste separation prevention ability as A when the solder paste is not separated after a lapse of 72 hours, and
- evaluating the solder paste separation prevention ability as B when the solder paste is not separated after a lapse of 48 hours and the solder paste is separated after a lapse of longer than 48 hours and shorter than 72 hours.
23 more elements
Dependencies are inferred from the claim text.