Composite containing platinum-alkaline earth metal alloy, fuel cell and water electrolysis cell containing the composite, and method of producing the composite
AssigneeDaegu Gyeongbuk Institute of Science and Technology
InventorsJong-Sung Yu, Caleb Gyan-Barimah
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Abstract
The present invention relates to a composite that is-cost-effective, has an excellent catalytic activity, and significantly improves stability compared to a pure platinum catalyst according to the related art. Specifically, the composite according to the present invention contains a carbon support and a binary alloy consisting of platinum and an alkaline earth metal supported on the carbon support which satisfies a specific condition in a Pt 4f X-ray photoelectron spectroscopy (XPS) spectrum of the binary alloy.
Claims10
A method of producing a composite, the method comprising:
- a step a) of preparing a mixed solution containing a platinum precursor, an alkaline earth metal precursor, a first reducing agent, and an aprotic organic solvent by dissolving the platinum precursor, the alkaline earth metal precursor, and the first reducing agent into the aprotic organic solvent;
- a step b) of preparing a colloid containing a synthetic product by performing a first heat treatment on the mixed solution at a temperature equal to or higher than a boiling point of the aprotic organic solvent and then naturally cooling the mixed solution;
- a step c) of obtaining the synthetic product by centrifuging the colloid;
- a step d) of mixing the synthetic product with a powdery second reducing agent, applying the synthetic product mixed with the powdery second reducing agent onto a carbon support, and then performing a second heat treatment in an inert reducing atmosphere to induce alloying between platinum and an alkaline earth metal to provide an alloyed synthetic product;
- and
- a step e) of removing impurities included in the alloyed synthetic product through an acid treatment.
Dependencies are inferred from the claim text.