# US 12,600,845 B2 · Propylene polymer composition

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- Number: US 12,600,845 B2
- Document ID: US12600845B2
- Status: Granted
- Kind: B2
- Application number: 17/911,938
- Filed: 2021-03-08
- Published: 2023-05-18
- Granted: 2026-04-14
- Earliest claimed: 2020-03-30
- Assignees: Basell Poliolefine Italia S.r.l.
- Applicants: Basell Poliolefine Italia S.R.L.
- Inventors: Davide Tartari
- Web page: https://patentgrep.com/patent/US12600845B2

## CPC

- C08F 10/06: Propene
- C08L 23/12: Polypropene
- C08L 2203/30: used for thermoforming
- C08L 2205/025: containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
- C08L 2207/02: Heterophasic composition
- C08L 2308/00: Chemical blending or stepwise polymerisation process with the same catalyst
- C08L 2314/02: Ziegler natta catalyst
- C08F: MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08L: COMPOSITIONS OF MACROMOLECULAR COMPOUNDS (compositions based on polymerisable monomers C08F, C08G; artificial filaments or fibres D01F; textile treating compositions D06)

## Abstract

A polypropylene composition made from or containing: A) From 96 wt % to 80 wt %; of a propylene homopolymer having a fraction insoluble in xylene at 25° C. greater than 90 wt %, based upon the total weight of the propylene homopolymer; and a melt flow rate, MFR, measured according to ISO 1133 at 230° C. with a load of 2.16 kg between 80.0 g/10 min and 300.0 g/10 min; and B) From 4 wt % to 20 wt %; of a propylene ethylene copolymer having an ethylene derived units content ranging from 18 wt % to 38 wt %, based upon the total weight of the propylene ethylene copolymer; wherein the polypropylene composition having: a melt flow rate, MFR, measured according to ISO 1133 at 230° C. with a load of 2.16 kg, between 80.0 g/10 min and 150.0 g/10 min; the sum of the amounts of A) and B) being 100 wt %.

## Claims

### Claim 1

A polypropylene composition comprising:
A) from 80 wt % to 96 wt %, of a propylene homopolymer, based upon the total weight of the polypropylene composition, having a fraction insoluble in xylene at 25° C. greater than 90 wt %, based upon the total weight of the propylene homopolymer; and
a melt flow rate, MFR, measured according to ISO 1133 at 230° C. with a load of 2.16 kg between 80.0 g/10 min and 300.0 g/10 min; and
B) From 4 wt % to 20 wt %; from 4 wt % to 20 wt %, of a propylene ethylene copolymer, based upon the total weight of the polypropylene composition, having an ethylene derived units content ranging from 18 wt % to 38 wt %, based upon the total weight of the propylene ethylene copolymer;
wherein the polypropylene composition has:
i) a xylene soluble fraction at 25° C. ranging from 5 wt % to 13.0 wt %, based upon the total weight of the polypropylene composition;
ii) an ethylene derived units content on the fraction insoluble in xylene at 25° C. ranging from 0.5 wt % to 3.5 wt %;
iii an ethylene derived units content on the fraction soluble in xylene at 25° C. ranging from 17.2 wt % to 27.0 wt %;
iv) the 13C NMR sequences PPE of the composition ranging from 3.50 mol % to 5.65 mol % and the 13C NMR sequences PEE measured on the fraction soluble in xylene at 25° C. ranging from 7.85 mol % to 11.00 mol %;
(v) a melt flow rate, MFR, measured according to ISO 1133 at 230° C. with a load of 2.16 kg, between 80.0 g/10 min and 150.0 g/10 min;
the sum of the amounts of A) and B) being 100 wt %; and
(vi) an intrinsic viscosity measured on the fraction soluble in xylene at 25° C. ranging from 0.9 to 2.3 dl/g.

### Claim 2 (depends on 1)

The polypropylene composition according to claim 1, wherein the propylene composition comprises from 85 wt % to 95 wt % of component A), based upon the total weight of the polypropylene composition, and from 5 wt % to 15 wt % of component B), based upon the total weight of the polypropylene composition.

### Claim 3 (depends on 1)

The polypropylene composition according to claim 1, wherein the xylene soluble fraction at 25° C. ranges from 6 wt % to 12 wt %, based upon the total weight of the polypropylene composition.

### Claim 4 (depends on 1)

The polypropylene composition according to claim 1, wherein, in component A), the melt flow rate, MFR, measured according to ISO 1133 at 230° C. with a load of 2.16 kg is between 100.0 g/10 min and 250.0 g/10 min.

### Claim 5 (depends on 1)

The polypropylene composition according to claim 1, wherein, in component B), the melt flow rate, MFR, measured according to ISO 1133 at 230° C. with a load of 2.16 kg, ranges from 90.0 g/10 min and 130.0 g/10 min.

### Claim 6 (depends on 1)

The polypropylene composition according to claim 1, wherein the ethylene derived units content on the fraction insoluble in xylene at 25° C. ranges from 0.8 wt % to 2.5 wt %.

### Claim 7 (depends on 1)

The polypropylene composition according to claim 1, wherein the ethylene derived units content on the fraction soluble in xylene at 25° C. ranges from 17.8 wt % to 21.3 wt %.

### Claim 8 (depends on 1)

The polypropylene composition according to claim 1, wherein the 13C NMR sequences PPE range from 3.80 mol % to 5.00 mol % and the 13C NMR sequences PEE measured on the fraction soluble in xylene at 25° C. range from 8.00 mol % to 10.80 mol %.

### Claim 9 (depends on 1)

The polypropylene composition according to claim 1, wherein the melt flow rate, MFR, measured according to ISO 1133 at 230° C. with a load of 2.16 kg is between 90.0 g/10 min and 130.0 g/10 min.

### Claim 10 (depends on 1)

The polypropylene composition according to claim 1, wherein the propylene composition comprises from 93 wt % to 87 wt % of component A), based upon the total weight of the polypropylene composition, and from 7 wt % to 13 wt % of component B), based upon the total weight of the polypropylene composition.

### Claim 11 (depends on 1)

The polypropylene composition according to claim 1, wherein the xylene soluble fraction at 25° C. ranges from 7 wt % to 11 wt %, based upon the total weight of the polypropylene composition.

### Claim 12 (depends on 1)

The polypropylene composition according to claim 1, wherein, in component A), the melt flow rate, MFR, measured according to ISO 1133 at 230° C. with a load of 2.16 kg is between 150.0 g/10 min and 220.0 g/10 min.

### Claim 13 (depends on 1)

The polypropylene composition according to claim 1, wherein, in component B), the melt flow rate, MFR, measured according to ISO 1133 at 230° C. with a load of 2.16 kg, ranges from 95.0 g/10 min and 120.0 g/10 min.

### Claim 14 (depends on 1)

The polypropylene composition according to claim 1, wherein the intrinsic viscosity measured on the fraction soluble in xylene at 25° C. ranges from 1.1 to 2.0 dl/g.

### Claim 15 (depends on 1)

An injection molded article comprising the propylene composition according to claim 1.
