Organic light emitting diode and organic light emitting device including the same

An organic light emitting diode, comprising:

• a first electrode;
• a second electrode facing the first electrode;
• and
• a first emitting part including a first red emitting material layer and positioned between the first and second electrodes,
• wherein the first red emitting material layer includes a first compound, a second compound and a third compound,
• wherein the first compound is represented by Formula 1-1:
• wherein in Formula 1-1:
• M is molybdenum (Mo), tungsten (W), rhenium (Re), ruthenium (Ru), osmium (Os), rhodium (Rh), iridium (Ir), palladium (Pd), platinum (Pt) or silver (Ag);
• each of A and B is a carbon atom;
• R is an unsubstituted or substituted C1-C20 alkyl group, an unsubstituted or substituted C1-C20 alkyl silyl group, an unsubstituted or substituted C3-C30 alicyclic group, an unsubstituted or substituted C3-C30 hetero alicyclic group, an unsubstituted or substituted C6-C30 aromatic group or an unsubstituted or substituted C3-C30 hetero aromatic group;
• each of X1 to X11 is independently a carbon atom, CR1 or N;
• only one of:
• a ring (a) with X3-X5, Y1 and A;
• or a ring (b) with X8-X11, Y2 and B is formed;
• and
• if the ring (a) is formed,
• each of X3 and Y1 is a carbon atom,
• X6 and X7 or X7 and X8 forms an unsubstituted or substituted C3-C30alicyclic ring, an unsubstituted or substituted C3-C30 hetero alicyclic ring, an unsubstituted or substituted C6-C30 aromatic ring or an unsubstituted or substituted C3-C30 hetero aromatic ring;
• and
• Y2 is BR2, CR2R3, C═O, SiR2R3, GeR2R3, PR2, P═O, O, S, SO2, Se, SeO2, Te, TeO2, or NRa, wherein Ra is an unsubstituted or substituted C1-C20 alkyl group or an unsubstituted or substituted C6-C30 aromatic group;
• if the ring (b) is forms,
• each of X8 and Y2 is a carbon atom,
• X1 and X2 or X2 and X3 forms an unsubstituted or substituted C3-C30 alicyclic ring, an unsubstituted or substituted C3-C30 hetero alicyclic ring, an unsubstituted or substituted C6-C30 aromatic ring or an unsubstituted or substituted C3-C30 hetero aromatic ring;
• and
• Y1 is BR2, CR2R3, C═O, SiR2R3, GeR2R3, PR2, P═O, O, S, SO2, Se, SeO2, Te, TeO2, or NRa, wherein Ra is an unsubstituted or substituted C1-C20 alkyl group or an unsubstituted or substituted C6-C30 aromatic group,
• each of R1 to R3 is independently hydrogen, protium, deuterium, tritium, a halogen atom, a hydroxyl group, a cyano group, a nitro group, an amidino group, a hydrazine group, a hydrozone group, an unsubstituted or substituted C1-C20 alkyl group, an unsubstituted or substituted C2-C20 alkenyl group, an unsubstituted or substituted C2-C20 alkynyl group, an unsubstituted or substituted C1-C20 alkoxy group, an amino group, an unsubstituted or substituted C1-C20 alkyl amino group, an unsubstituted or substituted C1-C20 alkyl silyl group, a carboxyl group, a nitrile group, an isonitrile group, a sulfanyl group, a phosphino group, an unsubstituted or substituted C3-C30 alicyclic group, an unsubstituted or substituted C3-C30 hetero alicyclic group, an unsubstituted or substituted C6-C30 aromatic group or an unsubstituted or substituted C3-C30 hetero aromatic group,
• optionally,
• two adjacent R1, and/or R2 and R3 form an unsubstituted or substituted C3-C30 alicyclic ring, an unsubstituted or substituted C3-C30 hetero alicyclic ring, an unsubstituted or substituted C6-C30 aromatic ring or an unsubstituted or substituted C3-C30 hetero aromatic ring;
• is an auxiliary ligand;
• m is an integer of 1 to 3;
• n is an integer of 0 to 2;
• and
• m+n is an oxidation number of M,
• wherein the second compound is represented by Formula 2-1:
• wherein in Formula 2-1:
• one of X12 and X13 is a nitrogen atom (N), and the other one of X12 and X13 is an oxygen atom (O) or a sulfur atom (S);
• each of R4, R5 and R6 is independently selected from the group consisting of an unsubstituted or substituted C6-C30 aryl group and an unsubstituted or substituted C3-C30 heteroaryl group;
• and
• L is selected from the group consisting of an unsubstituted or substituted C6-C30 arylene group and an unsubstituted or substituted C3-C30 heteroarylene group;
• and
• a is 0 or 1,
• wherein the third compound is represented by Formula 3-1:
• wherein in Formula 3-1:
• X is NR8, O or S,
• R8 is selected from the group consisting of an unsubstituted or substituted C1-C10 alkyl group, an unsubstituted or substituted C6-C30 aryl group and an unsubstituted or substituted C3-C30 heteroaryl group, and
• R7 is selected from the group consisting of an unsubstituted or substituted C6-C30 aryl group and an unsubstituted or substituted C3-C30 heteroaryl group.