Cathode for an electrochemical cell including at least one cathode additive
AssigneeDuracell U.S. Operations, Inc.
InventorsAlexander Boris Shelekhin, Freddy Arthur Barnabas
Life of this patent
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Abstract
The invention is directed towards a cathode. The cathode includes an electrochemically active cathode material and at least one cathode additive. The at least one cathode additive includes a head group and at least one hydrocarbon tail group. The head group includes at least one p-element atom that is bonded to a second p-element atom. The at least one p-element atom has an electronegativity and the second p-element atom has an electronegativity. The electronegativity of the at least one p-element atom is different from the electronegativity of the second p-element atom.
Claims20
A cathode comprising:
- an electrochemically active cathode material;
- at least one cathode additive, wherein the at least one cathode additive is a boronic acid, an amine oxide, a phosphine oxide, a sulfoxide, a sulfone, or a sultaine,
- and the at least one cathode additive comprises at least one hydrocarbon tail group bound to the boron atom of boronic acid, the nitrogen atom of the amine oxide, the phosphorus atom of the phosphine oxide, the sulfur atom of the sulfoxide, the sulfur atom of the sulfone, or the nitrogen atom of the sultaine;
- wherein the electrochemically active cathode material comprises a manganese electrochemically active material and a nickel electrochemically active material,
- wherein the manganese electrochemically active material is chosen from one or more in the group of manganese oxide, manganese dioxide, electrolytic manganese dioxide (EMD), chemical manganese dioxide (CMD), high power electrolytic manganese dioxide (HP EMD), lambda manganese dioxide, gamma manganese dioxide, beta manganese dioxide, and mixtures thereof;
- and
- the nickel electrochemically active material is chosen from one or more in the group of nickel oxide, nickel oxyhydroxide, cobalt oxyhydroxide-coated nickel oxyhydroxide, delithiated layered lithium nickel oxide, partially delithiated layered nickel oxide, beta-nickel oxyhydroxide, gamma-nickel oxyhydroxide, intergrowths of beta-nickel oxyhydroxide, intergrowths of gamma-nickel oxyhydroxide, intergrowths of beta-nickel oxyhydroxide and gamma-nickel oxyhydroxide, cobalt oxyhydroxide-coated beta-nickel oxyhydroxide, cobalt oxyhydroxide-coated gamma-nickel oxyhydroxide, cobalt oxyhydroxide-coated intergrowths of beta-nickel oxyhydroxide and gamma-nickel oxyhydroxide, and mixtures thereof.
A battery comprising:
- a housing;
- an anode;
- a cathode, the cathode comprising:
- an electrochemically active cathode material;
- and,
- at least one cathode additive, wherein the at least one cathode additive is a boronic acid, an amine oxide, a phosphine oxide, a sulfoxide, a sulfone or a sultaine,
- and the at least one cathode additive comprises at least one hydrocarbon tail group bound to the boron atom of the boronic acid, the nitrogen atom of the amine oxide, the phosphorus atom of the phosphine oxide, the sulfur atom of the sulfoxide, the sulfur atom of the sulfone, or the nitrogen atom of the sultaine;
- a separator between the anode and the cathode;
- and
- an electrolyte;
- wherein the electrochemically active cathode material comprises a manganese electrochemically active material and a nickel electrochemically active material,
- wherein the manganese electrochemically active material is chosen from one or more in the group of manganese oxide, manganese dioxide, electrolytic manganese dioxide (EMD), chemical manganese dioxide (CMD), high power electrolytic manganese dioxide (HP EMD), lambda manganese dioxide, gamma manganese dioxide, beta manganese dioxide, and mixtures thereof;
- and
- the nickel electrochemically active material is chosen from one or more in the group of nickel oxide, nickel oxyhydroxide, cobalt oxyhydroxide-coated nickel oxyhydroxide, delithiated layered lithium nickel oxide, partially delithiated layered nickel oxide, beta-nickel oxyhydroxide, gamma-nickel oxyhydroxide, intergrowths of beta-nickel oxyhydroxide, intergrowths of gamma-nickel oxyhydroxide, intergrowths of beta-nickel oxyhydroxide and gamma-nickel oxyhydroxide, cobalt oxyhydroxide-coated beta-nickel oxyhydroxide, cobalt oxyhydroxide-coated gamma-nickel oxyhydroxide, cobalt oxyhydroxide-coated intergrowths of beta-nickel oxyhydroxide and gamma-nickel oxyhydroxide, and mixtures thereof.
Dependencies are inferred from the claim text.