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US 12,596,303 B2Granted
Resist composition and pattern forming process
AssigneeShin-Etsu Chemical Co., Ltd.
InventorsJun Hatakeyama, Masahiro Fukushima
Life of this patent
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Abstract
A resist composition comprising a base polymer comprising repeat units having a salt structure consisting of a sulfonic acid anion bonded to a polymer backbone and a sulfonium cation having an acid labile group of triple bond-bearing tertiary ester type as the acid generator exhibits a high sensitivity and reduced LWR or improved CDU.
Claims8
A resist composition comprising a base polymer comprising repeat units (a) having a salt structure consisting of a sulfonic acid anion bonded to a polymer backbone and a sulfonium cation having the formula (1):
- wherein p is 0 or 1, q is an integer of 0 to 4, r is 1 or 2, s is an integer of 1 to 3,
- R1 is a single bond, ether bond, thioether bond or ester bond,
- R2 is a single bond or a C1-C20 alkanediyl group which may contain fluorine or to hydroxy,
- R3 and R4 are each independently a C1-C12 saturated hydrocarbyl group, C2-C8 alkenyl group, C2-C8 alkynyl group or C6-C12 aryl group, which may contain oxygen or sulfur, R3 and R4 may bond together to form a ring with the carbon atom to which they are attached,
- R5 is hydrogen, or a C1-C12, saturated hydrocarbyl group or C6-C18 aryl group, which may contain at least one moiety selected from hydroxy, C1-C6 saturated hydrocarbyloxy, C2-C6 saturated hydrocarbyloxycarbonyl, nitro, cyano, fluorine, chlorine, bromine, iodine, amino, trifluoromethyl, trifluoromethoxy, and trifluoronethylthio, with the proviso that R5 is not hydrogen when R3 is substituted or unsubstituted phenyl,
- R6 is hydroxy, carboxy, nitro, cyano, fluorine, chlorine, bromine, iodine, amino, or a C1-C20 saturated hydrocarbyl group, C1-C20 saturated hydrocarbyloxy group, C2-C20 saturated hydrocarbylcarbonyloxy group, C2-C20 saturated hydrocarbyloxycarbonyl group, or C1-C4 saturated hydrocarbylsulfonyloxy group, which may contain at least one moiety selected from fluorine, chlorine, bromine, iodine, hydroxy, amino and ether bond, and
- R7 is a C1-C20 hydrocarbyl group which may contain a heteroatom, in case of s=1, two groups R may be the same or different and may bond together to form a ring with the sulfur atom to which they are attached.
4 more elements
Dependencies are inferred from the claim text.