Flux and production method of steel product with hot-dip Zn—Al—Mg coating using said flux
AssigneeNippon Steel Corporation
InventorsKoutarou Ishii, Takao Tsujimura
Life of this patent
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Abstract
Provided is a technique that can produce a hot dip Zn—Al—Mg-based alloy coated steel product with a good plating appearance, without the need for heating of a steel product prior to immersion in a hot dip plating bath. Flux (11) for hot dip Zn—Al—Mg-based alloy plating contains: ZnCl2; and a low-reactive chloride which has low reactivity with respect to Mg in a plating bath and contains at least two chlorides selected from the compound group consisting of alkali metal chlorides and alkaline-earth metal chlorides, and a composition of the ZnCl2 and the low-reactive chloride is adjusted so that a liquidus temperature of the flux is 450° C. or lower.
Claims7
A flux for hot dip Zn—Al—Mg-based alloy plating, comprising:
- ZnCl2;
- and
- a low-reactive chloride having lower reactivity with Mg in a plating bath than the ZnCl2, the low-reactive chloride containing at least two chlorides selected from the compound group consisting of alkali metal chlorides and alkaline-earth metal chlorides, the low-reactive chloride being a chloride having free energy of formation that is lower than that of MgCl2,
- said flux being in a pellet form and substantially not containing NH4Cl and substantially not containing NaF,
- a composition of the ZnCl2 and the low-reactive chloride being adjusted so that a liquidus temperature of said flux is 450° C. or lower even in a case where all of the ZnCl2 contained in said flux has been substituted by MgCl2,
- the low-reactive chloride containing NaCl, and KCl, the flux containing an auxiliary chloride in an amount of more than 0% by mass and not more than 7.5% by mass in total, the auxiliary chloride including at least one chloride among a chloride of Sn, a chloride of Pb, and a chloride of Bi, and
- where a total mass of (i) the ZnCl2 and (ii) the low-reactive chloride is assumed to be 100 parts by mass,
- a contained amount of ZnCl2 being not less than 52.5% by mass and not more than 74.1% by mass,
- a total contained amount of the NaCl and KCl being not less than 25.9% by mass and not more than 47.5% by mass, and
- a ratio of a mass of KCl to a mass of NaCl (KCl/NaCl) being 0.15 or more and 11.5 or less.
A flux for hot dip Zn—Al—Mg-based alloy plating, comprising:
- ZnCl2;
- and
- a low-reactive chloride having lower reactivity with Mg in a plating bath than the ZnCl2, the low-reactive chloride containing at least two chlorides selected from the compound group consisting of alkali metal chlorides and alkaline-earth metal chlorides, the low-reactive chloride being a chloride having free energy of formation that is lower than that of MgCl2,
- the flux being in a pellet form and substantially not containing NH4Cl and substantially not containing NaF, and
- a composition of the ZnCl2 and the low-reactive chloride being adjusted so that a liquidus temperature of said flux is 450° C. or lower even in a case where all of the ZnCl2 contained in said flux has been substituted by MgCl2,
- wherein:
- the low-reactive chloride contains NaCl and KCl;
- a contained amount of the ZnCl2 is not less than 40.0% by mass and less than 52.5% by mass, and
- a total contained amount of the low-reactive chloride is more than 47.5% by mass and not more than 60.0% by mass;
- and
- a ratio (KCl/NaCl) of a mass of the KCl to a mass of the NaCl is 1.25 or more.
Dependencies are inferred from the claim text.