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US 12,595,396 B2Granted
Acid resistant filter media
AssigneeEntegris, Inc.
InventorsJames Hamzik, KwokShun Cheng, Jad A. Jaber, Nicholas J. Filipancic
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Abstract
Provided are certain membranes useful in the filtration of liquids and removal of various contaminants therein. In certain aspects the membranes have as one component a polyamide such as Nylon 11 and/or Nylon 12. Also provided is methodology for manufacturing such membranes and their use in filtration and purification of liquids. Membranes of the disclosure thus prepared exhibit superior acid stability when compared to polyamide membranes prepared from Nylon 6 or Nylon 6,6.
Claims12
A composite porous filter membrane comprising:
- a porous hydrophobic polymeric filter media having a coating thereon which at least partially coats surfaces throughout the porous hydrophobic polymeric filter media,
- wherein said coating is a polyamide polymer possessing a repeat unit structure of the formula —[(CH2)xC(O)NH]n—, wherein x is an integer of from about 8 to 12, and n represents the number of repeat units in the polyamide polymer, and
- wherein the composite porous filter membrane has the following characteristics:
- (i) a surface energy of from greater than 30 to 100 dynes/cm;
- (ii) an isopropanol flowtime of about 150 to about 20,000 seconds/500 mL, measured at 14.2 psi;
- (iii) a bubble point of about 20 to about 200 psi, when measured using ethoxy-nonafluorobutane HFE 7200 at a temperature of about 22° C.;
- (iv) a capacity to bind Ponceau S dye of between about 1 and about 30 μg/cm2 and the capacity to bind methylene blue dye (MB DBC) of between about 1 and about 30 μg/cm2;
- and
- (v) after exposure of the composite porous filter membrane to a >96% formic acid solution for 24 hours and flushing of the composite porous filter membrane with de-ionized water until a stable pH is obtained, the composite porous filter membrane retaining the surface energy of from greater than 30 to 100 dynes/cm.
6 more elements
Dependencies are inferred from the claim text.