# US 12,595,384 B1 · Polymer latex for matte films

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- Number: US 12,595,384 B1
- Document ID: US12595384B1
- Status: Granted
- Kind: B1
- Application number: 18/418,853
- Filed: 2024-01-22
- Granted: 2026-04-07
- Earliest claimed: 2021-01-05
- Assignees: Swimc LLC
- Applicants: Swimc LLC
- Inventors: Gamini S. Samaranayake; Shailesh S. Shah; Joseph J. Kestner; Kimberly A. Koglin; Tom Wendland; Margaret Patterson
- Web page: https://patentgrep.com/patent/US12595384B1

## CPC

- C09D 7/42: Gloss-reducing agents
- B01J 13/14: Polymerisation; cross-linking
- C08F 220/1804: {C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate}
- C09D 7/65: macromolecular (C09D7/41-C09D7/48 take precedence)
- C09D 7/69: {Particle size larger than 1000 nm}
- C09D 7/70: {characterised by shape, e.g. fibres, flakes or microspheres}
- C09D 133/04: Homopolymers or copolymers of esters {(C09D143/04 takes precedence)}
- C08L 2207/53: Core-shell polymer
- C09D: COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR (cosmetics A61K; processes for applying liquids or other fluent materials to surfaces, in general, B05D; staining wood B27K5/02; glazes or vitreous enamels C03C; natural resins, French polish, drying-oils, driers, turpentine, per se, C09F; polishing compositions other than French polish, ski waxes C09G; adhesives or use of materials as adhesives C09J; materials for sealing or packing joints or covers C09K3/10; materials for stopping leaks C09K3/12; processes for the electrolytic or electrophoretic production of coatings C25D)
- B01J: CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- C08F: MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08L: COMPOSITIONS OF MACROMOLECULAR COMPOUNDS (compositions based on polymerisable monomers C08F, C08G; artificial filaments or fibres D01F; textile treating compositions D06)

## Abstract

A waterborne coating composition including a novel polymer latex and methods of preparing the polymer latex for the waterborne coating composition. The disclosed polymer latex, when incorporated into the waterborne coating composition, reduces gloss, and achieves a matte appearance without the need for and/or with reduced amounts of traditional inorganic matting additives. In one approach, the polymer latex disclosed herein includes latex particles having a core/shell arrangement configured to not only participate in film formation but also impact surface morphology of dried films to produce the low gloss coatings.

## Claims

### Claim 1

A method of preparing an aqueous suspension of organic particles having a core and shell, the method comprising:
forming a pre-emulsion of one or more first monomers and an oil soluble free radical initiator in the presence of a colloidal dispersant, the one or more first monomers configured to form a polymer having a glass transition temperature (Tg) of about 80° C. or greater;
homogenizing the pre-emulsion to form an emulsion having an average particle diameter of about 3 to about 12 microns;
polymerizing the emulsion to form intermediate microsuspension of polymeric core particles having an average particle diameter of about 5 to about 12 microns;
forming a second pre-emulsion with one or more second monomers having a surface tension greater than the surface tension of the intermediate polymer particles and configured to form a polymer having a glass transition temperature of about 30° C. or less;
polymerizing the one or more second monomers of the second pre-emulsion in the presence of the intermediate polymer particles to form a polymeric shell at least partially surrounding the intermediate polymer particles and forming an aqueous suspension of organic particles having a core and shell; and
wherein the organic particles have an average diameter of about 10 to about 50 microns.

### Claim 2 (depends on 1)

The method of claim 1, wherein the colloidal dispersant includes polyvinyl alcohol, polyvinyl pyrrolidone, hydroxyethyl cellulose, hydroxyl propyl starch, or combinations thereof.

### Claim 3 (depends on 1)

The method of claim 1, wherein the one or more first monomers include styrene, divinyl benzene, methyl(meth)acrylate, hexane diol diacrylate, tert-butyl(meth)acrylate, sec-butyl(meth)acrylate, ethylhexyl(meth)acrylate, butyl (meth)acrylate, iso-bornyl (meth)acrylates, or combinations thereof.

### Claim 4 (depends on 3)

The method of claim 3, wherein the one or more second monomers include alkyl(meth)acrylates, (meth)acrylic acid, vinyl acetates, acrylamides, alkyl amino (meth)acrylate, allyl (meth)acrylates, diacetone acrylamide, acetoacetyloxy ethyl(meth)acrylate, ethylhexyl(meth)acrylate, or combinations thereof.

### Claim 5 (depends on 1)

The method of claim 1, wherein the aqueous suspension of organic particles is combined with a primary binder latex to form a waterborne coating composition having a pigment volume concentration (PVC) of about 28 or less and the waterborne coating composition, when dried as a film, exhibits a 60-degree gloss value of 5 or less and an 85-degree sheen value of 10 or less and with the polymeric shell of the organic particles combining with the primary binder latex to coalesce as the coating film and the polymeric core of the organic particles remaining as a particle within the dried coating film.

### Claim 6 (depends on 5)

The method of claim 5, wherein the waterborne coating composition includes about 20 to about 40 weight percent of the primary binder latex and about 2 to about 15 weight percent of the organic particles.

### Claim 7 (depends on 6)

The method of claim 6, wherein the waterborne coating composition is substantially free of inorganic extender particles.

### Claim 8 (depends on 7)

The method of claim 7, wherein the waterborne coating composition has a PVC of about 15 to about 26.