# US 12,595,350 B2 · Composition of plastic material and process for treating plastic materials for forming said composition > Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt - Number: US 12,595,350 B2 - Document ID: US12595350B2 - Status: Granted - Kind: B2 - Application number: 18/011,451 - Filed: 2021-06-16 - Published: 2023-08-24 - Granted: 2026-04-07 - Earliest claimed: 2020-06-18 - Assignees: ENI S.p.A.; Versalis S.P.A. - Applicants: Eni S.P.A.; Versalis S.P.A. - Inventors: Francesco Scavello; Nicola Vecchini; Riccardo Felisari; Armando Galeotti; Daniele Balducci; Stefania Guidetti; Erica Montanari - Web page: https://patentgrep.com/patent/US12595350B2 ## CPC - C08J 11/16: by treatment with inorganic material (C08J11/14 takes precedence) - C08K 3/26: Carbonates; Bicarbonates - C08J 2323/06: Polyethene - C08J 2323/12: Polypropene - C08J 2325/06: Polystyrene - C08J 2327/06: Homopolymers or copolymers of vinyl chloride - C08J 2367/02: Polyesters derived from dicarboxylic acids and dihydroxy compounds; (C08J2367/06 takes precedence) - C08J 2377/00: Characterised by the use of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Derivatives of such polymers - C08K 2003/262: {Alkali metal carbonates} - Y02W 30/62: Plastics recycling; Rubber recycling - C08J: WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H (working, e.g. shaping, of plastics B29) - C08K: Use of inorganic or non-macromolecular organic substances as compounding ingredients (paints, inks, varnishes, dyes, polishes, adhesives C09) - Y02W: CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT ## Abstract A plastic composition includes a plastic material with a halogen content less than or equal to 0.5% by mass with respect to the plastic material, oligomers derived from the plastic contained in the plastic material, halogenated salts, and hydrocarbon. A related process for producing a composition of plastic material includes the steps of forming a composition; bringing the composition at a temperature between 150° C. and 450° C., and keeping the composition obtained in the temperature range for a time between 10 seconds and 30 minutes to form a final composition. The inerting agent is added during the process in an amount such that the ratio between the sum of the moles of the alkali metals belonging to group IA and the sum of the moles of halogen contained in the plastic material is at most 20:1. ## Claims ### Claim 1 A composition of plastic material which comprises: plastic material with a halogen content less than or equal to 0.5% by mass with respect to the plastic material, oligomers derived from the plastic contained in said plastic material, said oligomers being generated from the thermal degradation of said plastic material, halogenated salts, and hydrocarbons. ### Claim 2 (depends on 1) The composition according to claim 1, wherein the hydrocarbons are selected from heavy distillates. ### Claim 3 (depends on 1) The composition according to claim 1, wherein the hydrocarbon is vacuum residue. ### Claim 4 (depends on 1) The composition according to claim 1, wherein the halogenated salts are selected from alkali metal salts of group IA. ### Claim 5 (depends on 4) The composition according to claim 4, wherein the halogenated salts are selected from the group consisting of chlorides of alkali metals of group IA, fluorides of alkali metals of group IA, bromides of alkali metals of group IA, and iodides of alkali metals of group IA. ### Claim 6 (depends on 5) The composition according to claim 5, wherein the chlorides of the alkali metals of group IA are selected from the group consisting of lithium chloride, sodium chloride, and potassium chloride. ### Claim 7 (depends on 5) The composition according to claim 5, wherein the bromides of the alkali metals of group IA are selected from the group consisting of lithium bromide, sodium bromide, and potassium bromide. ### Claim 8 (depends on 1) The composition according to claim 1, wherein the minimal mixing area of the composition produced is less than or equal to 0.03 mm2. ### Claim 9 (depends on 8) The composition according to claim 8, wherein the minimal mixing area varies between 0.001 mm2 and 0.02 mm2. ### Claim 10 A process for producing a composition of plastic material includes the following steps: forming a composition by heating and mixing at the same time or in separate stages, in one or more devices which include devices for heating and mixing, a plastic material, including a recycled one, containing halogenated components, an inerting agent and a hydrocarbon stream, bringing said composition at a temperature comprised between 150° C. and 450° C., and keeping the composition thus obtained within said temperature range for a time comprised between 10 seconds and 30 minutes, thus forming a final composition; wherein the inerting agent is added during the process in such an amount that the ratio between the sum of the moles of the alkali metals belonging to group IA and the sum of the moles of halogen contained in the plastic material is at most 20:1. ### Claim 11 (depends on 10) The process according to claim 10, wherein the plastic material contains organic or inorganic compounds. ### Claim 12 (depends on 11) The process according to claim 11, wherein the organic and inorganic compounds are selected from the group consisting of metallic materials, ceramic materials, building materials; insulation materials; paper and cardboard; food residues; and soil materials. ### Claim 13 (depends on 10) The process according to claim 10, wherein the plastic material comprises plastics for at least 60% by weight, said % calculated with respect to the overall weight of the plastic material. ### Claim 14 (depends on 13) The process according to claim 13, wherein the plastic material comprises plastics for at least 80% by weight, said % calculated with respect to the overall weight of the plastic material. ### Claim 15 (depends on 14) The process according to claim 14, wherein the plastic material comprises plastics for 100% by weight, said % calculated with respect to the overall weight of the plastic material. ### Claim 16 (depends on 10) The process according to claim 10, wherein said plastic material is PLASMIX. ### Claim 17 (depends on 10) The process according to claim 10, wherein the plastic material is in the form of flakes and has a median size (D50) greater than 0.2 cm; or wherein the plastic material is compacted in the form of pellets obtained by extrusion of the flakes through a die plate with holes of diameter from 2 to 20 mm. ### Claim 18 (depends on 17) The process according to claim 17, wherein the plastic material in the form of flakes is characterized by an apparent density greater than 50 kg/m3 measured according to ASTM D1895-17 method C, “before loading” density measurement. ### Claim 19 (depends on 17) The process according to claim 17, wherein the plastic material in the form of pellets is characterized by an apparent density greater than 200 kg/m3 measured according to ASTM D1895-17 method B. ### Claim 20 (depends on 10) The process according to claim 10, wherein the composition of the plastics contained in said plastic material comprises at least one of the following components selected from the group consisting of, where the percentages are expressed by weight with respect to the total of the plastics: Polyethylene: 10-100% Polypropylene: 0-50% Polystyrene: 0-50% Polyesters: 0-20% The sum of cellulosic, urethane and polyamide polymers: 0-20% Inorganic fillers: 0-30% and Chlorinated polymers in amounts such that the weight of chlorine is comprised between 0.05 and 15% with respect to the total weight of the plastic materials. ### Claim 21 (depends on 10) The process according to claim 10, wherein the ratio between the sum of the moles of the alkali metals belonging to group IA and the sum of the moles of halogen contained in the plastic material varies between 10:1 and 1:1. ### Claim 22 (depends on 21) The process according to claim 21, wherein the ratio between the sum of the moles of the alkali metals belonging to group IA and the sum of the moles of halogen contained in the plastic material varies between 3:1 to 3:2. ### Claim 23 (depends on 10) The process according to claim 10, wherein the inerting agent is added in such an amount that simultaneously: the ratio between the sum of the moles of alkali metals belonging to group IA and the sum of the moles of halogen contained in the plastic material is at most 20:1 and the ratio between the mass of alkali metals belonging to group IA and the mass of plastic material is at least 1:1000. ### Claim 24 (depends on 10) The process according to claim 10, wherein the inerting agent is an alkali metal belonging to group IA of the periodic table, selected from the group consisting of lithium, sodium, potassium, rubidium, caesium, and combinations thereof. ### Claim 25 (depends on 24) The process of claim 24, wherein the metal is a mixture of lithium and metallic sodium. ### Claim 26 (depends on 10) The process according to claim 10, wherein the inerting agent is a sodium compound selected from the group consisting of carbonate, bicarbonate, carboxylates, biphenyl, cyclopentadienyl, butyl, butyral, oxide, hydroxide, alkyl sulfonates, and alkylbenzene sulfonates. ### Claim 27 (depends on 26) The process according to claim 26, wherein the sodium carboxylate compounds are selected from the group consisting of stearates, palmitates, pivalates, and octoates. ### Claim 28 (depends on 10) The process according to claim 10, wherein the inerting agent is a lithium compound selected from the group consisting of methyl, butyl, aspartate, acetate, carbonate, bicarbonate, stearates, oxide, and hydroxide. ### Claim 29 (depends on 10) The process according to claim 10, wherein the inerting agent also comprises ketals up to 10% by weight with respect to the total weight of the inerting agent. ### Claim 30 (depends on 10) The process according to claim 10, wherein the hydrocarbon stream is the vacuum residue. ### Claim 31 (depends on 10) The process according to claim 10, which is conducted by extrusion. ### Claim 32 (depends on 10) The process according to claim 10, which is conducted in a two-stage mode which comprises: a first stage in which the plastic material and inerting agent are mixed to form a first composition; then a second stage in which said first composition is mixed with a hydrocarbon stream forming a final composition of plastic material. ### Claim 33 (depends on 32) The process according to claim 32, wherein the plastic material is preheated to a temperature of at least 150° C. ### Claim 34 (depends on 32) The process according to claim 32, wherein the apparatuses are extruders. ### Claim 35 (depends on 10) The process according to claim 10, which is conducted in one or more apparatuses selected from the group consisting of extruders, static mixers, dynamic mixers, and stirred reactors. ### Claim 36 (depends on 10) The process according to claim 10, wherein the minimal mixing area measured on the final composition of plastic material is less than or equal to 0.03 mm2. ### Claim 37 (depends on 10) The process according to claim 10, which further comprises the step of converting by thermal or catalytic conversion processes, optionally in the presence of inerting agents, said final compositions of plastic material into hydrocarbon products. ### Claim 38 (depends on 10) The process according to claim 10, which further comprises the step of converting by visbreaking processes, optionally in the presence of inerting agents, said final compositions of plastic material into hydrocarbon products. ### Claim 39 (depends on 10) The process according to claim 10, which further comprises the step of converting said final compositions of plastic material by cracking or hydrocracking processes optionally in the presence of inerting agents into hydrocarbon products. ### Claim 40 (depends on 10) The process according to claim 10, which further comprises the step of converting said final compositions of plastic material by catalytic and non-catalytic hydroconversion processes, optionally in the presence of inerting agents, into hydrocarbon products. ### Claim 41 (depends on 10) The process according to claim 10, which further comprises the step of converting said final compositions of plastic material into hydrocarbon products by catalytic hydroconversion processes with Eni Slurry Technology (EST), optionally in the presence of inerting agents. ### Claim 42 (depends on 10) The process according to claim 10, wherein the hydrocarbon products are selected from the group consisting of light distillates, heavy distillates, and gases. ### Claim 43 (depends on 42) The process according to claim 42, wherein the hydrocarbon products are selected from the group consisting of naphtha, atmospheric gas oil (AGO), light vacuum gas oil (LGVO) and heavy gas oil (HVGO).