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US 12,595,343 B2Granted
Additive mixtures for rheology modification of polymers
AssigneeBASF SE
InventorsSebastien Villeneuve, Peter Nesvadba, Daniel Mueller, Raphael Dabbous
Life of this patent
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Abstract
A mixture can be used for modifying the rheology of polymeric substrates. The mixture contains a hydroxylamine ester and an isocyanate functionalized with a thio compound.
Claims18
A composition comprising:
- (a) a compound of formula (1) or (2)
- wherein
- G1, G2, G3 and G4 are each independently of each other C1-C4 alkyl, or G1 and G2 together or G3 and G4 together are pentamethylene;
- G1′, G2′, G3′ and G4′ are each independently of each other C1-C4 alkyl, or G1′ and G2′ together or G3′ and G4′ together are pentamethylene;
- G5, G6, G5′ and G6′ are each independently of each other hydrogen or C1-C4 alkyl;
- and
- X and X′ are independently of each other hydrogen, C1-C18 alkyl, C2-C18 alkenyl, —O—C1-C18 alkyl, —NH—C1-C18 alkyl, —N(C1-C6 alkyl)2, phenyl, phenoxy or —NH-phenyl,
- m is 1 or 2, and
- when m is 1, R1 is C2-C8 alkylene, C2-C8 hydroxyalkylene or C4-C36 acyloxyalkylene, or
- when m is 2, R1 is (—CH2)2C(CH2—)2, and
- R1′ is hydrogen, C1-C8 alkyl, C1-C8 hydroxyalkyl or a group of formula —(C═O)—C1-C40 alkyl, or
- O—R1′ together with a —CH— group linking them are a group —(C═O)—,
- (b) a compound of formula (3)
- wherein
- A is based on an organic isocyanate, wherein radical(s) —S—R are introduced by reaction with isocyanate groups,
- R is C2-C40 alkyl which is optionally substituted and/or interrupted, and
- n is equal to or greater than 1, and
- (c) a polymeric substrate.
15 more elements
A composition comprising:
- a compound of formula (1) or (2)
- wherein
- G1, G2, G3 and G4 are each independently of each other C1-C4 alkyl, or G1 and G2 together or G3 and G4 together are pentamethylene;
- G1′, G2′, G3′ and G4′ are each independently of each other C1-C4 alkyl, or G1′ and G2′ together or G3′ and G4′ together are pentamethylene;
- G5, G6, G5′ and G6′ are each independently of each other hydrogen or C1-C4 alkyl;
- and
- X and X′ are independently of each other hydrogen, C1-C18 alkyl, C2-C18 alkenyl, —O—C1-C18 alkyl, —NH—C1-C18 alkyl, —N(C1-C6 alkyl)2, phenyl, phenoxy or —NH-phenyl,
- m is 1 or 2, and
- when m is 1, R1 is C2-C8 alkylene, C2-C8 hydroxyalkylene or C4-C36 acyloxyalkylene, or
- when m is 2, R1 is (—CH2)2C(CH2—)2, and
- R1′ is hydrogen, C1-C8 alkyl, C1-C8 hydroxyalkyl or a group of formula —(C═O)—C1-C40 alkyl, or
- —O—R1′ together with a —CH— group linking them are a group —(C═O)—, and
- a compound of formula (3)
- wherein
- A is based on an organic isocyanate, wherein radical(s) —S—R are introduced by reaction with isocyanate groups,
- R is C2-C40 alkyl which is optionally substituted and/or interrupted, and
- n is equal to or greater than 1.
14 more elements
Dependencies are inferred from the claim text.