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US 12,590,203 B2Granted
Curable oxamate esters and formulations made therefrom
AssigneeHenkel AG & Co. KGaA
InventorsLaxmisha M. Sridhar, Kevin J. Welch
Life of this patent
Estimating the term…
Abstract
The disclosure relates to oxamate esters and formulations made therefrom, and to methods of making both the oxamate esters and the formulations.
Claims3
A two-part curable composition comprising:
- a part A comprising an oxamate ester represented by Structure I:
- wherein R1 is polydimethylsiloxane;
- L1 is selected from the group consisting of (1) a covalent bond, (2) a hydrocarbylene segment having 1 to 100 carbon atoms, and (3) a heterocarbylene segment having 1 to 100 carbon atoms, the latter two of which may be optionally interrupted with one or more nitrogen, oxygen or sulfur atoms;
- R2 is selected from the group consisting of H, alkyl, cycloalkyl, aryl, aralkyl, and heterocyclic;
- R3 is selected from the group consisting of alkyl, haloalkyl, cycloalkyl, aryl, aralkyl, and heterocyclic;
- and
- n1 is 2-20;
- and
- a part B comprising an amine represented by Structure II:
- wherein R4 is selected from the group consisting of a polymeric, prepolymeric or monomeric silicone, aliphatic, aromatic, heterocyclic, alicyclic, ether, and ester;
- R5 is selected from the group consisting of H, alkyl, cycloalkyl, aryl, aralkyl, and heterocyclic;
- L2 is selected from the group consisting of (1) a covalent bond (2) a hydrocarbylene segment having 1 to 100 carbon atoms and (3) a heterocarbylene segment having 1 to 100 carbon atoms, the latter two of which may be optionally interrupted with one or more nitrogen, oxygen or sulfur atoms;
- and
- n2 is 2-20.
11 more elements
A two-part curable composition comprising:
- a part A comprising an oxamate ester represented by Structure VII:
- wherein R, R1, R2, R3, and R4 are each independently selected from the group consisting of alkyl, aryl, or aralkyl;
- L is alkylene, with or without interruption by one or more O atoms;
- and
- n is greater than or equal to 2 and m is 2-1,000;
- and
- a part B comprising an amine represented by Structure II:
- wherein R4 is selected from the group consisting of a polymeric, prepolymeric or monomeric silicone, aliphatic, aromatic, heterocyclic, alicyclic, ether, and ester;
- R5 is selected from the group consisting of H, alkyl, cycloalkyl, aryl, aralkyl, and heterocyclic;
- L2 is selected from the group consisting of (1) a covalent bond, (2) a hydrocarbylene segment having 1 to 100 carbon atoms, and (3) a heterocarbylene segment having 1 to 100 carbon atoms, the latter two of which may be optionally interrupted with one or more nitrogen, oxygen or sulfur atoms;
- and
- n2 is 2-20.
9 more elements
A two-part curable composition comprising:
- A part A comprising an oxamate ester represented by Structure I:
- wherein R1 is selected from the group consisting of a polymer or a prepolymer;
- L1 does not attach to R1 of the polymer or the prepolymer at its terminus and is selected from the group consisting of (1) a covalent bond, (2) a hydrocarbylene segment having 1 to 100 carbon atoms, and (3) a heterocarbylene segment having 1 to 100 carbon atoms, the latter two of which may be optionally interrupted with one or more nitrogen, oxygen or sulfur atoms;
- R2 is selected from the group consisting of H, alkyl, cycloalkyl, aryl, aralkyl, and heterocyclic;
- R3 is selected from the group consisting of alkyl, haloalkyl, cycloalkyl, aryl, aralkyl, and heterocyclic;
- and
- n1 is 2-20;
- and
- a part B comprising an amine represented by Structure II:
- wherein R4 is selected from the group consisting of a polymeric, prepolymeric or monomeric silicone, aliphatic, aromatic, heterocyclic, alicyclic, ether, and ester;
- R5 is selected from the group consisting of H, alkyl, cycloalkyl, aryl, aralkyl, and heterocyclic;
- L2 is selected from the group consisting of (1) a covalent bond, (2) a hydrocarbylene segment having 1 to 100 carbon atoms, and (3) a heterocarbylene segment having 1 to 100 carbon atoms, the latter two of which may be optionally interrupted with one or more nitrogen, oxygen or sulfur atoms;
- and
- n2 is 2-20.
11 more elements
Dependencies are inferred from the claim text.