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US 12,590,047 B2Granted
Method for producing fluorine-containing olefin
AssigneesThe University of Tokyo, AGC Inc.
InventorsKyoko Nozaki, Midori Akiyama, Kenta Mori, Takashi Okazoe, Yuichiro Ishibashi, Ko Inada
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Abstract
A production method of producing a fluorine-containing olefin by allowing a first olefin represented by the following Formula (1) and a second olefin to react with each other in the presence of a ruthenium compound represented by the following Formula (X) is provided.
Claims15
A production method of producing a fluorine-containing olefin comprising:
- allowing a first olefin represented by the following Formula (1) and a second olefin different from Formula (1) of the first olefin to react with each other in the presence of a ruthenium compound represented by the following Formula (X):
- wherein, in Formula (X),
- A represents an atom group necessary for forming a 6- or 7-membered nitrogen-containing heterocyclic ring comprising two nitrogen atoms, an aromatic or aliphatic ring may be condensed to the nitrogen-containing heterocyclic ring, and A and the aromatic or aliphatic ring condensed to the nitrogen-containing heterocyclic ring may comprise a substituent,
- each of R1 and R2 independently represents an alkyl group, an aryl group, or an aralkyl group,
- each of Y1 and Y2 independently represents an anionic ligand,
- L′ represents a neutral electron-donating ligand,
- p represents 0 or 1, and
- each of Z1 and Z2 independently represents a hydrogen atom, a halogen atom, a monovalent hydrocarbon group having a carbon number of from 1 to 20, or a monovalent hydrocarbon group having a carbon number of from 1 to 20 and comprising one or more atoms selected from the group consisting of a halogen atom, an oxygen atom, a nitrogen atom, a sulfur atom, a phosphorus atom, and a silicon atom, Z1 and Z2 may be bonded to each other to form a ring, and either or both of Z1 and Z2, and L1 may be chemically bonded to each other,
- wherein, in Formula (1), each of A1, A2, and A3 independently represents a hydrogen atom, a fluorine atom, a chlorine atom, or a fluorine-containing alkyl group having a carbon number of from 1 to 10.
6 more elements
Dependencies are inferred from the claim text.