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US 12,585,189 B2Granted
Method for manufacturing cured film and use of the same
AssigneeMerck Patent GmbH
InventorsTakashi Sekito, Shigemasa Nakasugi, Hiroshi Yanagita, Taku Hirayama
Life of this patent
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Abstract
[Problem] To provide a method for manufacturing a cured film having high film density, high film hardness and high etching resistance. [Means for Solution] A method for manufacturing a cured film comprising (1) applying a composition (i) above a substrate; (2) forming a hydrocarbon-containing film from the composition (i); and (3) irradiating the hydrocarbon-containing film with plasma, electron beam and/or ion to form a cured film. Use of the cured film.
Claims14
A method for producing a cured film, comprising the steps of:
- (1) applying a (i) composition above a substrate;
- (2) (i) forming a hydrocarbon-containing film from the composition;
- and
- (3) irradiating the hydrocarbon-containing film with an electron beam or ions to form a cured film
- provided that (i) the composition comprises (A) a hydrocarbon-containing compound, and (B) a solvent;
- the (A) hydrocarbon-containing compound comprises a structural unit (A1) represented by the following formula (A1):
- wherein Ar11 is a C6-60 hydrocarbon substituted or unsubstituted with R11 (provided that Ar11 does not contain a fused aromatic ring);
- R11 is a C1-20 linear, branched or cyclic alkyl, amino or alkylamino;
- R12 is I, Br or CN;
- p11 is a number of 0 to 5, p12 is a number of 0 to 1, q11 is a number of 0 to 5, q12 is a number of 0 to 1, r11 is a number of 0 to 5, and s11 is a number from 0 to 5;
- p11, q11 and r11 are not simultaneously 0 in one constitutional unit;
- in the case electron beam irradiation is performed in step (3),
- acceleration voltage is 2 kV to 200 kV, or the irradiation dose is 100 kGy to 5,000 kGy,
- in the case ions are irradiated in the step (3),
- the elemental species of the ions to be irradiated is hydrogen, boron, carbon, nitrogen, a rare gas, or a mixture of any of these,
- the acceleration voltage is 3 to 1000 kV, or
- the irradiation dose is 1013 to 1018 ions/cm 2, wherein the cured film formed in the step (3) has an intensity ratio R=ID/IG of 0.35 to 0.90 in Raman spectroscopic analysis (measured with a laser wavelength of 514.5 nm).
14 more elements
Dependencies are inferred from the claim text.