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US 12,585,160 B2Granted
Liquid-crystalline medium
AssigneeMerck Patent GmbH
InventorsHoo-Yong Lee, Hyun-Jin Yoon
Life of this patent
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Abstract
A liquid-crystalline media having a negative dielectric anisotropy and a high clearing point as specified herein, is suitable for use of in switchable optical cells in window elements, in particular laminated window elements.
Claims14
A process for the preparation of a window element, comprising
- providing a switchable optical cell which comprises a switchable layer interposed between a first transparent substrate and a second transparent substrate, wherein the switchable optical cell is electrically switchable, and wherein the switchable optical cell has a layer structure comprising, in sequence, the first transparent substrate, a first electrode layer, a first alignment layer, the switchable layer, a second alignment layer, a second transparent electrode layer, and the second transparent substrate,
- wherein the switchable layer comprises a liquid-crystalline medium having a negative dielectric anisotropy, a clearing point of greater than 140° C. to 170° C., and an optical anisotropy Δn in the range of from 0.075 to 0.1, and the switchable layer is a homeotropically aligned liquid crystal layer comprising the liquid-crystalline medium, wherein in the presence of an electric field the switchable layer has a twisted configuration or a supertwisted configuration, wherein the liquid-crystalline medium comprises three or more dichroic dyes, and wherein the switchable layer has a thickness in the range from 4 μm to 10 μm, and
- laminating the switchable optical cell to a third substrate via a thermoplastic interlayer arranged between the first or second transparent substrate of the switchable optical cell and the third substrate, wherein, during the laminating, heating to a temperature of 110° C. or more is carried out;
- and
- wherein the first transparent substrate and the second transparent substrate are made of plastic and are optically isotropic, and the third substrate is curved, made of glass, and is optically isotropic and transparent.
2 more elements
A window element, comprising a switchable optical cell having a layer structure comprising in this order:
- a first transparent substrate,
- a first electrode layer,
- a first alignment layer,
- a switchable layer,
- a second alignment layer,
- a second electrode layer, and
- a second transparent substrate,
- wherein the switchable layer comprises a liquid-crystalline medium having a negative dielectric anisotropy, a clearing point of greater than 140° C. to 170° C., and an optical anisotropy Δn in the range of from 0.075 to 0.1, wherein the liquid-crystalline medium comprises three or more dichroic dyes, and the switchable layer is a homeotropically aligned liquid crystal layer comprising the liquid-crystalline medium, and wherein the switchable layer has a thickness in the range from 4 μm to 10 μm,
- wherein the switchable optical cell is laminated to a third substrate via a thermoplastic interlayer arranged between the first or second transparent substrate of the switchable optical cell and the third substrate, and wherein the switchable optical cell is electrically switchable, and
- wherein the first transparent substrate and the second transparent substrate are made of plastic and are optically isotropic, and the third substrate is curved, made of glass, and is optically isotropic and transparent, and
- wherein in the presence of an electric field the switchable layer has a twisted configuration or a supertwisted configuration.
8 more elements
Dependencies are inferred from the claim text.