Preparation method of super absorbent polymer
AssigneeLG Chem, Ltd.
InventorsChang Hun Lee, Jiyoon Jeong, Jung Eun Kim
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Abstract
Provided is a method for preparing superabsorbent polymer, which includes conducting first surface crosslinking of a base resin powder while raising the temperature to a first temperature, in the presence of a first surface crosslinking agent; conducting second surface crosslinking of the first surface crosslinked base resin powder at a second temperature. According to the method of the present technology, surface crosslinking strength of the resulting superabsorbent polymer is increased, thus enabling preparation of superabsorbent polymer having little or no decline in absorbency under load even after anti-caking agent treatment.
Claims13
A method for preparing superabsorbent polymer comprising:
- conducting crosslinking polymerization of water soluble ethylenically unsaturated monomers having acid groups of which at least a part are neutralized, in the presence of a polymerization initiator and an internal crosslinking agent, to form hydrogel polymer comprising a crosslinked polymer of water soluble ethylenically unsaturated monomers;
- drying, grinding and classifying the hydrogel polymer to obtain base resin powder;
- conducting first surface crosslinking of the base resin powder while raising to a first temperature, in the presence of a first surface crosslinking agent to form a first surface crosslinked base resin powder;
- and
- conducting second surface crosslinking of the first surface crosslinked base resin powder at a second temperature, in the presence of a second surface crosslinking agent, to form superabsorbent polymer particles,
- wherein the first temperature is 180° C. or more, and the second temperature is 120° C. to 150° C., and
- the second surface crosslinking agent comprises an epoxy-based compound having larger weight average molecular weight than that of the first surface crosslinking agent, and capable of forming a covalent bond at the second temperature.
Dependencies are inferred from the claim text.