Polyethylene powder and molded article
AssigneeAsahi Kasei Kabushiki Kaisha
InventorKazuya Shikata
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Abstract
Provided is a polyethylene powder that completes swelling in a short time, offers a uniform appearance or shape of a molded article, and produces a molded article with smooth surface even by high-speed molding. The polyethylene powder satisfies (requirements 1 and 2). (Requirement 1): an intrinsic viscosity (IV) is 1.5 dL/g or more and 34.0 dL/g or less, and (requirement 2): a ratio γ0/γ1 of an elastic limit strain γ0 at a swelling time t (h) of 0 hours to an elastic limit strain γ1 at a swelling time t (h) of 1 hour is 0.80 or more and 0.95 or less, wherein the ratio is obtained from a strain dependence test.
Claims12
A polyethylene powder satisfying the following requirement 1 and requirement 2:
- requirement 1:
- an intrinsic viscosity (IV) measured in accordance with IS01628-3 (2010) is 1.5 dL/g or more and 34.0 dL/g or less, and
- requirement 2:
- a ratio γ0/γ1 of an elastic limit strain γ0 at a swelling time t (h) of 0 hours to an elastic limit strain γ1 at a swelling time t (h) of 1 hour is 0.80 or more and 0.95 or less, wherein the ratio is obtained from a strain dependence test for dynamic viscoelasticity under the following Conditions for measurement of viscoelasticity of slurry and the swelling time t (h) is as defined below:
- Conditions for measurement of viscoelasticity of slurry
- Measurement apparatus:
- MARSIII manufactured by Thermo Fisher Scientific, Inc.
- Stage:
- 20 mmφ
- Plate:
- 20 mmφ parallel plate
- Gap:
- 0.5 mm
- Slurry composition:
- 30 parts by mass of the polyethylene powder and 70 parts by mass of liquid paraffin
- Conditions for measurement:
- the strain dependence test is conducted by the following steps 1 and 2:
- step 1 of keeping a temperature of a slurry at 100° C. for the swelling time t (h) in a nitrogen atmosphere on a sample stage;
- and
- step 2 of conducting the strain dependence test under conditions of 180° C. and a frequency of 1 Hz in a nitrogen atmosphere,
- Determination of elastic limit strain:
- an elastic limit strain γt is determined by a two-tangent method.
Dependencies are inferred from the claim text.