Zirconia pre-sintered body suitable for dental use
AssigneeKuraray Noritake Dental Inc.
InventorsShinichiro Kato, Yoshihisa Ito
Life of this patent
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Abstract
The present invention provides a zirconia pre-sintered body that can be fired into a sintered body having translucency and strength suited for dental use (particularly, at the dental clinic), even with a short firing time. The present invention relates to a zirconia pre-sintered body comprising: zirconia; and a stabilizer capable of inhibiting a phase transformation of zirconia, wherein the zirconia predominantly comprises a monoclinic crystal system, and the zirconia pre-sintered body comprises a plurality of layers that differ from each other in the content of the stabilizer relative to the total mole of the zirconia and the stabilizer.
Claims17
A zirconia pre-sintered body comprising:
- zirconia;
- and
- a stabilizer capable of inhibiting a phase transformation of zirconia,
- wherein the zirconia predominantly comprises a monoclinic crystal system,
- wherein the zirconia pre-sintered body comprises a plurality of layers that differ from each other in a content of the stabilizer relative to a total mol % of the zirconia and the stabilizer,
- wherein the stabilizer is yttria,
- wherein the zirconia pre-sintered body has a fraction fy of more than 0% as calculated from mathematical expression (1):
-
-
- f
- y
-
- (
- %
- )
- =
- I
- y
-
- (
- 1
-
- 1
-
- 1
- )
- I
- y
-
- (
- 1
-
- 1
-
- 1
- )
- +
- I
- m
-
- (
- 1
-
- 1
-
- 1
- )
- +
- I
- m
-
- (
- 1
-
- 1
- -
- 1
- )
- +
- I
- t
-
- (
- 1
-
- 1
-
- 1
- )
- +
- I
- c
-
- (
- 1
-
- 1
-
- 1
- )
- ×
- 100
- (
- 1
- )
- where Iy (111) represents a peak intensity of a (111) plane of the yttria about 2θ=29° in an X-ray diffraction pattern using CuKα radiation,
- Im (111) and Im (11-1) represent peak intensities of (111) plane and (11-1) plane, respectively, of the monoclinic crystal system of the zirconia in the X-ray diffraction pattern,
- It (111) represents a peak intensity of a (111) plane of a tetragonal crystal system of the zirconia in the X-ray diffraction pattern, and
- Ic (111) represents a peak intensity of a (111) plane of a cubic crystal system of the zirconia in the X-ray diffraction pattern, and
- wherein the fraction fy is 13% or less, and
- wherein, on a straight line extending along a first direction from one end to another end of the zirconia pre-sintered body, a content of the yttria relative to a total mol % of the zirconia and the yttria shows unchanging patterns of increase and decrease from the one end toward the other end, and a layer containing the one end has a fraction fy of 1% or more and a layer containing the other end has a fraction fy of 0.5% or more.
Dependencies are inferred from the claim text.