Back to results
US 12,582,978 B2Granted
Catalyst decontamination process
AssigneePraxair Technology, Inc.
InventorsRichard M. Kelly, Ashley Zachariah, Perry R. Pacouloute
Life of this patent
Estimating the term…
Abstract
Catalyst beds in refinery reactors require periodic change out due to build-up of contamination and loss of activity. The instant invention mists a liquid chemical solvent in nitrogen carrier gas to solubilize oils and heavy hydrocarbons and to further desorb light hydrocarbons and remove hydrogen sulfide (H2S), to effect decontamination. This process can be advantageously combined with nitrogen cool-down processes in preparation for catalyst unloading.
Claims20
A method for decontaminating a reactor system containing at least one catalyst comprising the steps of:
- a. providing a water-free carrier gas from a water-free carrier gas source at a first mass flow rate;
- b. providing a non-aqueous liquid solvent from a non-aqueous liquid solvent source at a second mass flow rate, and adding said solvent to said carrier gas to create a mist of liquid solvent droplets in carrier gas, wherein said non-aqueous liquid solvent and said carrier gas are provided at a mass flow rate ratio in the range 0.1:1 to 8:1;
- the mist has a temperature in the range 50 to 400° F. and a pressure in the range 50 to 500 psig, wherein a majority of the provided solvent remains a liquid phase in the mist, wherein greater than 50% of the provided solvent remains in liquid form in the mist;
- c. delivering said mist into the reactor system;
- and contacting the delivered mist with at least a first portion of catalyst, wherein the initial temperature of said at least a first portion of catalyst in the reactor is between 250 and 450° F. prior to delivering said solvent mist into the reactor system;
- and
- d. removing contaminants from the reactor system, wherein a substantial amount of said contaminants are solubilized by said solvent and removed from said reactor system in a vapor or liquid form.
4 more elements
Dependencies are inferred from the claim text.