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US 12,582,965 B2Granted
Preparation method of super absorbent polymer
AssigneeLG Chem, Ltd.
InventorsSeul Ah Lee, Yoon Jae Min, Ui Seok Chung, Gicheul Kim
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Abstract
The present disclosure relates to a preparation method of a super absorbent polymer. More specifically, it relates to a preparation method of a super absorbent polymer with improved permeability and anti-caking efficiency while having a high absorption rate by adding an additive having a specific structure to the hydrogel polymer polymerized in the presence of an encapsulated foaming agent, followed by coarse pulverization.
Claims15
A method of preparing a super absorbent polymer, comprising
- forming a hydrogel polymer by cross-linking polymerization of a water-soluble ethylene-based unsaturated monomer having at least partially neutralized acidic groups in the presence of an internal cross-linking agent, an encapsulated foaming agent, and a polymerization initiator;
- coarsely pulverizing the hydrogel polymer after mixing with a carboxylic acid-based additive;
- drying and pulverizing the coarsely pulverized hydrogel polymer to prepare a powdery base resin;
- and
- further cross-linking a surface of the powdery base resin in the presence of a surface cross-linking agent to form a surface cross-linked layer,
- wherein the carboxylic acid-based additive comprises at least one selected from the group consisting of a carboxylic acid represented by Chemical Formula 1 and a salt thereof:
- wherein in Chemical Formula 1,
- A is C5 to C21 alkyl,
- B1 is —OCO—, —COO—, or —COOCH(R1)COO—,
- B2 is —CH2—, —CH2CH2—, —CH(R2)—, —CH═CH—, or —C≡C—,
- R1 and R2 are each independently C1 to C4 alkyl,
- n is an integer of 1 to 3, and
- C is a carboxyl group.
10 more elements
Dependencies are inferred from the claim text.