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US 12,577,026 B2Granted
Abrasion resistant heat shrinkable multilayer film
AssigneeCryovac, Inc.
InventorsPrasanna U. Perera, Sonola Onasanya
Life of this patent
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Abstract
A multilayer heat-shrinkable film having a sealant layer and skin layer each including a linear low density polyethylene copolymer and a silicon dioxide, at least two substrate layers including an ethylene copolymer; and a core layer including a very low density polyethylene copolymer.
Claims13
A multilayer heat-shrinkable film comprising:
- a. a sealant layer comprising between 30-49.99 wt % of a homogeneous polyethylene copolymer having a density from 0.91 to 0.93 g/cm3, between 50-69.99 wt % ethylene/octene copolymer having a density from 0.93 to 0.95 g/cm3, and between 0.01-0.4 wt % of a member selected from the group consisting of natural silica, synthetic silica, ceramic spheres, diatomaceous earth, kaolin, and mica;
- b. at least two substrate layers comprising an ethylene/vinyl acetate copolymer;
- c. a core layer comprising between 70-90 wt % ethylene/octene copolymer having a density from 0.93 to 0.95 g/cm3, and between 10-30 wt % of a very low density ethylene/octene copolymer having a density less than 0.915 g/cm3, and
- d. a skin layer comprising between 30-39.99 wt % of a homogeneous ethylene/hexene copolymer having a density from 0.91 to 0.93 g/cm3, at least 10 wt % of a high density polyethylene homopolymer having a density of at least 0.95 g/cm3, and between 50-59.99 wt % ethylene/octene copolymer having a density from 0.93 to 0.95 g/cm3, and between 0.01-0.4 wt % of a member selected from the group consisting of natural silica, synthetic silica, ceramic spheres, diatomaceous earth, kaolin, and mica;
- wherein the multilayer heat-shrinkable film has an oxygen transmission rate of between 2000 to 9000 cm3 (STP)/(m2-day-1 atm) at 40° C. and 0% relative humidity measured in accordance with ASTM D3985.
2 more elements
A packaged product comprising:
- a. a support structure exhibiting a shape;
- b. a product situated within the support;
- c. a multilayer heat-shrinkable film encapsulating the support thereby isolating the product from an external environment;
- the multilayer heat-shrinkable film comprising:
- i. a sealant layer comprising between 30-49.99 wt % of a homogeneous polyethylene copolymer having a density from 0.91 to 0.93 g/cm3, between 50-69.99 wt % ethylene/octene copolymer having a density from 0.93 to 0.95 g/cm3, and between 0.01-0.4 wt % of a member selected from the group consisting of natural silica, synthetic silica, ceramic spheres, diatomaceous earth, kaolin, and mica;
- ii. at least two substrate layers comprising an ethylene/vinyl acetate copolymer;
- iii. a core layer comprising between 70-90 wt % ethylene/octene copolymer having a density from 0.93 to 0.95 g/cm3, and between 10-30 wt % of a very low density ethylene/octene copolymer having a density less than 0.915 g/cm3;
- and
- iv. a skin layer comprising between 30-39.99 wt % of a homogeneous ethylene/hexene copolymer having a density from 0.91 to 0.93 g/cm3, at least 10 wt % of a high density polyethylene homopolymer having a density of at least 0.95 g/cm3, and between 50-59.99 wt % ethylene/octene copolymer having a density from 0.93 to 0.95 g/cm3, and between 0.01-0.4 wt % of a member selected from the group consisting of natural silica, synthetic silica, ceramic spheres, diatomaceous earth, kaolin, and mica;
- wherein the multilayer heat-shrinkable film has an oxygen transmission rate of between 2000 to 9000 cm3 (STP)/(m2-day-1 atm) at 40° C. and 0% relative humidity measured in accordance with ASTM D3985.
7 more elements
A method for packaging a product comprising the steps of:
- a. providing a support structure which retains its shape while supporting a product;
- b. situating a product within the support;
- c. encapsulating the support with a multilayer heat-shrinkable film thereby isolating the product from an external environment;
- the multilayer heat-shrinkable film comprising:
- i. a sealant layer comprising between 30-49.99 wt % of a homogeneous polyethylene copolymer having a density from 0.91 to 0.93 g/cm3, between 50-69.99 wt % ethylene/octene copolymer having a density from 0.93 to 0.95 g/cm3, and between 0.01-0.4 wt % of a member selected from the group consisting of natural silica, synthetic silica, ceramic spheres, diatomaceous earth, kaolin, and mica;
- ii. at least two substrate layers comprising an ethylene/vinyl acetate copolymer;
- iii. a core layer comprising between 70-90 wt % ethylene/octene copolymer having a density from 0.93 to 0.95 g/cm3, and between 10-30 wt % of a very low density ethylene/octene copolymer having a density less than 0.915 g/cm3, and
- iv. a skin layer comprising between 30-39.99 wt % of a homogeneous ethylene/hexene copolymer having a density from 0.91 to 0.93 g/cm3, at least 10 wt % of a high density polyethylene homopolymer having a density of at least 0.95 g/cm3, and between 50-59.99 wt % ethylene/octene copolymer having a density from 0.93 to 0.95 g/cm3, and between 0.01-0.4 wt % of a member selected from the group consisting of natural silica, synthetic silica, ceramic spheres, diatomaceous earth, kaolin, and mica;
- wherein the multilayer heat-shrinkable film has an oxygen transmission rate of between 2000 to 9000 cm3 (STP)/(m2-day-1 atm) at 40° C. and 0% relative humidity measured in accordance with ASTM D3985.
6 more elements
Dependencies are inferred from the claim text.