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US 12,576,426 B2Granted
Multilayer body and method for producing multilayer body
AssigneeTaisei Kako Co., Ltd.
InventorsMuneaki Nabeta, Yoshihiro Matsushita, Kenji Ohnishi
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Abstract
An embodiment of the present invention relates to a multilayer body and a method for producing the multilayer body, and the multilayer body includes a metal base, and a cured layer 1, the cured layer 1 having a curing ratio of 70 to 90% on the metal base side, and the cured layer 1 having a curing ratio of 50 to 70% on the side opposite to the metal base side.
Claims13
A multilayer body comprising:
- a metal base comprising a metal base side;
- and a cured layer 1 on the metal base side of the metal base,
- the cured layer 1 having an internal curing ratio of 70 to 90% on the metal base side, and the cured layer 1 having a surface curing ratio of 50 to 65.2% on a side opposite to the metal base side,
- wherein the cured layer 1 is obtained by irradiating a curable composition with an ultraviolet light emitting diode (LED), the curable composition comprising a curable compound comprising an ethylenically unsaturated double bond (C═C) and a polymerization initiator that can initiate polymerization upon irradiation with the ultraviolet LED,
- wherein the curable compound is a bisphenol A-type epoxy(meth)acrylate and the polymerization initiator is an acylphosphine oxide photopolymerization initiator;
- wherein a thickness of the cured layer 1 is 5 to 10 microns (μm);
- wherein the curing ratios are calculated from the equation:
- Curing
-
- ratio
- [
- %
- ]
- =
- (
- 1
- -
- (
- (
- B
- ′
- /
- A
- ′
- )
- /
- (
- B
- /
- A
- )
- )
- ×
- 100
- wherein in an FT-IR spectrum of the curable composition, peak intensity of a peak assignable to a benzene ring at 1510 cm−1 is peak intensity A and peak intensity of a peak assignable to the ethylenically unsaturated double bond (C═C) at 1410 cm−1 is peak intensity B, and
- wherein in an FT-IR spectrum of the cured layer 1, peak intensity of a peak assignable to the benzene ring at 1510 cm−1 is peak intensity A′ and the peak intensity of the peak assignable to the ethylenically unsaturated double bond (C═C) at 1410 cm−1 is peak intensity B′,
- wherein the internal curing ratio on the metal base side is measured at 0.1× a thickness of the cured layer 1 away from a surface of the cured layer 1 adjoining to the metal base side of the metal base, assuming that a level of the surface of the cured layer 1 adjoining to the metal base side of the metal base is 0 μm, and
- wherein the surface curing ratio is measured at 0.9× a thickness of the cured layer 1 away from a surface adjoining to the metal base side of the metal base, assuming that a level of the surface of the cured layer 1 adjoining to the metal base side of the metal base is 0 μm.
35 more elements
Dependencies are inferred from the claim text.