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US 12,565,547 B2Granted
Dispersant for suspension polymerization, method for producing dispersant for suspension polymerization, and method for producing vinyl polymer particles
AssigneeKuraray Co., Ltd.
InventorShinsuke Nii
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Abstract
Provided by the present invention are a dispersant for suspension polymerization which enables production of vinyl polymer particles having a small particle diameter at a small added amount, a method for producing such a dispersant for suspension polymerization, and a method for producing vinyl polymer particles by using such a dispersant for suspension polymerization.
Claims19
A dispersant for suspension polymerization, comprising:
- a vinyl alcohol polymer having a structure represented by formula 1:
- wherein, in the formula 1, R1 represents an alkyl group having 1 to 4 carbon atoms;
- n is an integer of 1 to 10;
- and * denotes a site bonding to a part other than the structure represented by the formula 1 in the vinyl alcohol Polymer,
- wherein the dispersant comprises a powder having an average particle diameter of 100 μm or more 2,000 μm or less,
- wherein the dispersant comprises;
- particles A which have a particle diameter of 500 μm or more, and
- particles B which have a particle diameter of 220 μm or less,
- wherein a ratio (A/B) of an absorbance A of a 0.1% by mass aqueous solution of the particles A at an optical path length of 10 mm and a wavelength of 320 nm to an absorbance B of a 0.1% by mass aqueous solution of the particles B at the optical path length of 10 mm and the wavelength of 320 nm is 0.7 or more and 1.2 or less,
- wherein an average value PA of a roundness P, represented by formula 2, of 50 particles arbitrarily extracted from the particles of the dispersant which have a particle diameter of 100 μm or more and 1,000 μm or less is 0.1 or more and 0.8 or less:
- P
- =
- (
- ∑
- i
- =
- 1
- N
- r
- i
- )
- /
- NR
- 2
- wherein, in the formula 2, ri represents a radius of curvature of each corner of a particle of the 50 particles arbitrarily extracted;
- R represents a radius of a maximum inscribed circle of the particle;
- and N represents a number of corners of the particle, wherein in a case in which the number of corners of the particle is 9 or more, the radii of curvature of eight corners, in increasing order from a smallest radius of curvature, are adopted, and N is set to 8.
24 more elements
Dependencies are inferred from the claim text.