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US 12,565,422 B2Granted
Ammonia and urea production in reverse flow reactors
AssigneeExxonMobil Technology and Engineering Company
InventorsAnastasios I. Skoulidas, Everett J. O'Neal, Ian J. Laurenzi
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Abstract
Systems and methods are provided for using a reverse-flew reactor (or another reactor with flows in opposing directions at different parts of a process cycle) as part of a reaction system for production of ammonia and/or urea. Using a reverse flow reactor as part of an ammonia production process can provide a variety of advantages, including direct heating of the reaction environment, and simplified generation of multiple high-purity reagent streams for ammonia and/or urea synthesis.
Claims7
A method for performing reforming, comprising:
- reacting a fuel mixture comprising a fuel stream and an oxygen-containing stream under combustion conditions in a combustion zone within a reactor to form a flue gas and to heat one or more surfaces in a reaction zone to a regenerated surface temperature of 600° C. or more, the reaction zone comprising a catalyst composition, the oxygen-containing stream further comprising N2, the fuel mixture comprising 0.1 vol % or more O2 relative to a volume of the fuel mixture;
- separating, from the flue gas, an N2-containing stream comprising 95 vol % or more N2;
- exposing a hydrocarbon-containing stream to the catalyst composition in the reaction zone at the regenerated surface temperature under reforming conditions to form a reforming product stream comprising H2 and CO, a direction of flow for the hydrocarbon-containing stream within the reaction zone being reversed relative to a direction of flow for the fuel mixture;
- and
- forming an H2-containing stream comprising 50 vol % or more H2 from at least a portion of the reforming product stream;
- methanating at least a portion of the H2-containing stream to form a methanated stream;
- and
- exposing the methanated stream and at least a portion of the N2-containing stream to ammonia synthesis conditions to form an ammonia-containing product,
- i) wherein the reactor comprises a reverse flow reactor;
- ii) wherein the reactor comprises a reactor system, the reactor system comprising a recuperator portion and a portion including the reaction zone;
- or iii) a combination of i) and ii).
8 more elements
Dependencies are inferred from the claim text.