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US 12,559,377 B2Granted
Method of synthesizing a molecular sieve of MWW framework type
AssigneeExxonMobil Chemical Patents Inc.
InventorsSina Sartipi, Marc H. Anthonis, Aaron W. Peters, Mariame Akouche, Scott J. Weigel
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Abstract
Disclosed is a method of synthesizing a molecular sieve of MWW framework type, and molecular sieves so synthesized. The method comprises preparing a synthesis mixture for forming a molecular sieve of MWW framework type, said synthesis mixture comprising water, a silicon source, a source of a trivalent element X, a potassium cation source, a structure directing agent R, and a source of another alkali metal cation M.
Claims24
A method of synthesizing a molecular sieve of MWW framework type, the method comprising the steps of:
- a) preparing a synthesis mixture capable of forming a molecular sieve of MWW framework type, said synthesis mixture comprising water, a silicon source, a source of a trivalent element X, a potassium cation source, a structure directing agent R, a source of another alkali metal cation M, optionally a source of a pentavalent element Z, optionally a source of hydroxide ions, and optionally seed crystals, the synthesis mixture having the following molar ratio composition:
- Si:X2=8 to 18
- H2O:Si=5 to 100
- (M+K+):Si=0.1 to 0.5
- M:K+=1 to 10
- R:Si=0.1 to 1;
- b) heating said synthesis mixture under crystallization conditions for a time sufficient to form crystals of said molecular sieve of MWW framework type, said crystallization conditions including a temperature of from 100° C. to 220° C.;
- and
- c) recovering said crystals of the molecular sieve of MWW framework type from the synthesis mixture.
6 more elements
Dependencies are inferred from the claim text.