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US 12,552,735 B2Granted
Process for the synthesis of twin-tail triamines
AssigneeSyensqo SA
InventorsOlivier Back, Zhen Yan
Life of this patent
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Abstract
The invention relates to a new method for producing twin-tail triamines, preferably fatty twin-tail triamines. Furthermore, the present invention relates to the production of diamines obtained from internal ketones. These diamines may be used in the method for producing twin-tail triamines according to the invention. Finally, the invention relates to a new aldehyde compound, which is an intermediate product of the method for producing twin-tail triamines of the invention.
Claims18
A method for producing a twin-tail triamine having the formula (I)
- characterized in that in a first method step a diamine having the formula (II)
- is reacted with an aldehyde having the formula (III)
- to obtain an aldehyde having the formula (IV)
- which is further reacted, in a second method step, with an amine having the formula (V)
- under reductive amination conditions to obtain the twin-tail triamine according to formula (I), wherein
- R1 and R2 independently represent a C3-C27 aliphatic group,
- R3 and R4 either independently represent a C1-C8alkyl group, or are linked together to form a ring of formula
- wherein R4—R3 represents a divalent hydrocarbon radical containing from 2 to 10 carbon atoms,
- R5 and R6 either independently represent a C1-C8 alkyl group, or are linked together to form a ring of formula
- wherein R5-R6 represents a divalent hydrocarbon radical containing from 2 to 10 carbon atoms,
- R7, R8 and R9 independently represent hydrogen or a C1-C8 alkyl group, and
- E1 represents a linear or branched divalent hydrocarbon radical with 2 to 24 carbon atoms, which can be optionally substituted and/or interrupted by one or more heteroatom containing groups.
9 more elements
Dependencies are inferred from the claim text.