Method for forming multilayer coating film
AssigneesBASF Coatings GmbH, Nissan Motor Co., Ltd.
InventorsTakeshi Tsunoda, Tomoyuki Okamoto, Satoshi Watanabe, Naoki Kuriyama, Kouta Futamata, Takeshi Gotou, Chie Michiura
Life of this patent
Estimating the term…
Abstract
Disclosed herein is a method for forming a multilayer coating film by sequentially coating an intermediate coating material composition, a base coating material composition and a clear coating material composition on a metal for a motor vehicle body or resin material and then thermally curing the compositions, where the clear coating material composition is obtained by mixing a main agent (A) and a curing agent (B).
Claims16
A method for forming a multilayer coating film by sequentially coating an intermediate coating material composition, a base coating material composition and a clear coating material composition on a metal for a motor vehicle body, on which an electrodeposition coating material has been coated and a formed electrodeposition coating film has been completely baked, and then thermally curing, wherein the clear coating material composition is obtained by mixing a main agent (A) and a curing agent (B), the main agent (A) contains a hydroxy group-containing acrylic resin (A-1) as a main resin and a surface conditioner (A-2) at a quantity of 0.01-3.0 mass % relative to the mass of solid content in the hydroxy group-containing acrylic resin (A-1), the hydroxy group-containing acrylic resin (A-1) has a hydroxy value of 80-250 mg KOH/g, a mass average molecular weight of 1,000-30,000 and a solubility parameter (SP) value of 9.0-12.0, the surface conditioner (A-2) is a polymer which has a mass average molecular weight of 3,000-100,000 and is obtained by grafting an acrylic resin (A-2-i) and a resin (A-2-ii), the solubility parameter (SP) value of the acrylic resin (A-2-i) is 8.5-10.0, and the solubility parameter (SP) value of the resin (A-2-ii) is at least 2.0 higher than the solubility parameter (SP) value of the acrylic resin (A-2-i).
A method for forming a multilayer coating film by sequentially coating an intermediate coating material composition, a base coating material composition and a clear coating material composition on a resin material for a motor vehicle exterior, and then thermally curing, wherein the clear coating material composition is obtained by mixing a main agent (A) and a curing agent (B), the main agent (A) contains a hydroxy group-containing acrylic resin (A-1) as a main resin and a surface conditioner (A-2) at a quantity of 0.01-3.0 mass % relative to the mass of solid content in the hydroxy group-containing acrylic resin (A-1), the hydroxy group-containing acrylic resin (A-1) has a hydroxy value of 80-250 mg KOH/g, a mass average molecular weight of 1,000-30,000 and a solubility parameter (SP) value of 9.0-12.0, the surface conditioner (A-2) is a polymer which has a mass average molecular weight of 3,000-100,000 and is obtained by grafting an acrylic resin (A-2-i) and a resin (A-2-ii), the solubility parameter (SP) value of the acrylic resin (A-2-i) is 8.5-10.0, and the solubility parameter (SP) value of the resin (A-2-ii) is at least 2.0 higher than the solubility parameter (SP) value of the acrylic resin (A-2-i).
Dependencies are inferred from the claim text.